Electroless metallization of polyimides

This paper describes a new seeding process for electroless metallization of polyimides and other electroactive polymers. Polyimide films can be reduced electrochemically at an electrode surface or by contact with an appropriate reducing agent in an electrolyte solution. In the latter case, only the outer surface of the film undergoes reduction. Once the polyimide surface is reduced it then can mediate electron transfer to metal ions or metal complexes in solution causing metal to be deposited at the surface with concurrent reoxidation of the polyimide. 

This paper describes a process for activating polyimide surfaces for electroless metal plating. A thin surface region of a polyimide film can be electro-chemically reduced when contacted with certain reducing agent solutions. The electroactivity of polyimides is used to mediate electron transfer for depositing catalytic metal (e.g., Pd, Pt, Ni, Cu) seeds onto the polymer surface. The proposed metal deposition mechanism presented is based on results obtained from cyclic voltammetric, UV-visible, and Rutherford backscattering analysis of reduced and metallized polyimide films. This process allows blanket and full-additive metallization of polymeric materials for electronic device fabrication. 

The deposition of metals such as Pd, Pt, Ni, and Cu renders the surface active towards further metal deposition from conventional electroless metal plating baths. Well-adhering metal films can be formed on polyimides by this method. The main process steps for blanket metallization of a polyimide film, illustrated in Scheme I, involve polymer reduction, metal seeding, and electroless metal plating. Specific details of each process step are provided in the discussion below. 

DYCOstrate. A different approach to small via creation has been taken by Dyconex AG of Switzerland. After ground and power patterns are formed on the panel, and the panel is oxide-treated, polyimide-backed copper foil is laminated on the panel. Holes in the copper are formed by a chemical etching process, and the insulating polyimide material underneath the holes is removed by plasma etching. PWBs made in such a way are called DYCOstrate. In other, similar technologies, different dielectric materials are used, and they are removed by alkaUne solutions. The rest of the process is similar to that for SLC that is, holes are metallized and a thick copper deposition is made by electroless or galvanic plating, and the circuit pattern is formed by a tent-and-etch process (see Fig. 5.5). 

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