Elastic moduli response

The glass-ceramic phase assemblage, ie, the types of crystals and the proportion of crystals to glass, is responsible for many of the physical and chemical properties, such as thermal and electrical characteristics, chemical durabiUty, elastic modulus, and hardness. In many cases these properties are additive for example, a phase assemblage comprising high and low expansion crystals has a bulk thermal expansion proportional to the amounts of each of these crystals. 

Example 10 Response to Instantaneous Valve Closing Compute the wave speed and maximum pressure rise for instantaneous valve closing, with an initial velocity of 2,0 m/s, in a 4-in Schedule 40 steel pipe with elastic modulus 207 X 10 Pa, Repeat for a plastic pipe of the same dimensions, with E = 1.4 X 10 Pa. The liquid is water with P = 2.2 X 10 Pa and p = 1,000 kg/m. For the steel pipe, D = 102,3 mm, b = 6,02 mm, and the wave speed is... 

Dynamic mechanical tests measure the response or deformation of a material to periodic or varying forces. Generally an applied force and its resulting deformation both vary sinusoidally with time. From such tests it is possible to obtain simultaneously an elastic modulus and mechanical damping, the latter of which gives the amount of energy dissipated as heat during the deformation of the material. 

The response of a plastic to an applied stress depends on the temperature and the time at that temperature to a much greater extent than does that of a metal or ceramic. The variation of an amorphous TP over an extended temperature range can be exemplified by the behavior of its elastic modulus as a function of temperature. 

The spring is elastically storing energy. With time this energy is dissipated by flow within the dashpot. An experiment performed using the application of rapid stress in which the stress is monitored with time is called a stress relaxation experiment. For a single Maxwell model we require only two of the three model parameters to describe the decay of stress with time. These three parameters are the elastic modulus G, the viscosity r and the relaxation time rm. The exponential decay described in Equation (4.16) represents a linear response. As the strain is increased past a critical value this simple decay is lost. 

TMA measures the mechanical response of a polymer looking at (1) expansion properties including the coefficient of linear expansion, (2) tension properties such as measurement of shrinkage and expansion under tensile stress, i.e., elastic modulus, (3) volumetric expansion, i.e., specific volume, (4) single-fiber properties, and (5) compression properties such as measuring the softening or penetration under load. 

We have written Eq. (5.4) with variables grouped as they are in order to define two very important quantities. The first quantity in parentheses is called the modulus—or in this case, the tensile modulus, E, since a tensile force is being applied. The tensile modulus is sometimes called Young s modulus, elastic modulus, or modulus of elasticity, since it describes the elastic, or recoverable, response to the applied force, as represented by the springs. The second set of parentheses in Eq. (5.4) represents the tensile strain, which is indicated by the Greek lowercase epsilon, e. The strain is defined as the displacement, r — rp, relative to the initial position, rp, so that it is an indication of relative displacement and not absolute displacement. This allows comparisons to be made between tensile test performed at a variety of length scales. Equation (5.4) thus becomes... 

The modulus from a nanoindentation test is often reported in terms of a reduced elastic modulus, Er, to take into account the fact that at this size scale, the elastic response of the probe tip, E(, as well as the modulus of the test material, E, must be considered ... 

TMA measures the mechanical responses of a polymer as a function of temperature. Typical measurements include (1) expansion properties, i.e., the expansion of a material leading to the calculation of the linear expansion coefficient (2) tension properties, i.e., the shrinkage and expansion of a material under tensile stress e.g., elastic modulus (3) dilatometric properties, i.e., the volumetric expansion within a confining medium e.g., specific volume ... 

Dynamic mechanical tests measure the response of a material to a periodic force or its deformation by such a force. One obtains simultaneously an elastic modulus (shear, Young s, or bulk) and a mechanical damping. Polymeric materials are viscoelastic-i.e., they have some of the characteristics of both perfectly elastic solids and viscous liquids. When a polymer is deformed, some of the energy is stored as potential energy, and some is dissipated as heat. It is the latter which corresponds to mechanical damping. 

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