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If the monomer concentration is kept constant then the kinetic chain length relationship [Pg.22]

As the rate of polymerisation increases with increase in temperature the molecular weight will decrease [Pg.22]

Examples for styrene in xylene using AZDN at 50°C and assuming f=l. [I] = 1 X 10 mole [M] = 1 mole litre [Pg.23]

Therefore molecular weight of styrene polymer = 186 x 104 = 19,000. For termination by disproportionation, I=v. [Pg.23]

See other pages where Effect of Reaction Conditions on Chain Length is mentioned: [Pg.22]