Effect densification

Another interesting possibility suggested by these reactions is that some of them appear to produce whiskers in-situ. Besides the possibilities of directly producing a product body, such reactions n y be used to prepare powders. This, in turn, would Introduce another microstructural issue and opportunity in processing, that is, the size of the composite particles and how this effects densification and resultant composite performance. 

Ewsuk K G 1992 Effects of trapped gases on ceramic-fiiied-giass composite densification Solid State Phenomena voi 25-26, ed A C D Chakiader and J A Lund (Brookfieid, VT Trans-Tech) pp 63-72 (Proc. Sintering 91)... 

Chemical stabilization involves removing the concentration of surface hydroxyls and surface defects, such as metastable three-membered rings, below a critical level so that the surface is not stressed by rehydroxylation in use. Thermal stabilization involves reducing the surface area sufficiently to enable the material to be used at a given temperature without reversible stmctural changes. The mechanisms of thermal and chemical stabilization are interrelated because of the extreme effects that surface hydroxyls and chemisorbed water have on stmctural changes. Full densification of gels, such as the... 

Densification is also influenced by the presence of supporting electrolyte. As shown in the last line of Table II, the relative densification in acidified cupric sulfate is less than that in binary cupric sulfate solution. In the case of the supported redox reaction, that is, in the presence of KOH or NaOH, the migration effect makes the density difference larger than that expected from overall reaction stoichiometry. 

Precursor Structure Effects. The precursor structure can impact a broad range of properties, including crystallization temperature, the formation of intermediate phases during thermal treatment and film density, among other properties. Table 2.4 reports some of the key precursor properties that may affect densification and crystallization behavior, as well as the final film microstructure. 

Researchers who have focused more on understanding cause-effect relationships in solution processing have given attention to film drying and pyrolysis behavior, densification processes, and nucleation and growth into the desired crystalline state. Both thermodynamic and kinetic factors associated with the phase transformation from the amorphous state to the crystalline state have been considered.11 119 Control of these factors can lead to improvements in the ability to influence the microstructure. It is noted that in the previous sentence, influence has been carefully chosen, since the ability to manipulate the factors that govern the nature of the phase transformation to the extent that full control of the microstructure is possible remains to be demonstrated. However, trends in characteristics such as film orientation and columnar versus uniaxial grains have certainly already been achieved.120... 

The majority of work done on VGCF reinforced composites has been carbon/carbon (CC) composites [20-26], These composites were made by densifying VGCF preforms using chemical vapor infiltration techniques and/or pitch infiltration techniques. Preforms were typically prepared using furfuryl alcohol as the binder. Composites thus made have either uni-directional (ID) fiber reinforcement or two-directional, orthogonal (0/90) fiber reinforcement (2D). Composite specimens were heated at a temperature near 3000 °C before characterization. Effects of fiber volume fraction, composite density, and densification method on composite thermal conductivity were addressed. The results of these investigations are summarized below. 

An example where one metal melts before the densification process, is the formation of bronze from a 90 10 weight percentage mixture of copper and tin. The tin melts at a temperature of 505 K, and the liquid immediately wets the copper particles, leaving voids in the compact. The tin then diffuses into the copper particles, leaving further voids due to the Kirkendall effect. The compact is therefore seen to swell before the final sintering temperature of 1080 K is reached. After a period of homogenization dictated by the criterion above, the alloy shrinks on cooling to leave a net dilatation on alloy formation of about 1%. 

The major directions of changing porosity in DRP are schematically shown in Figure 9.22 [3,61], As a starting point, one can use the porosity of DRP of monospheres s0 = 0.36-0.42. Values of >s0 increase with particles anisotropy, roughness, and internal porosity, and also with the influence of wall effects at K> 0.1, and DIH > 0.05. Values of < (J are characteristic for polydis-perse particles when denser zones with ordered or unidirectional packings are formed, and also under forced densification and deformation of particles, correspondingly. 

Effects of particle size and pressure on the reactive sintering were studied by Gobran et al. (2004). The synthesis of RuAl was described it was observed that reactive systems containing low-melting constituents such as aluminium are assisted in densification by the formation of a transient liquid phase. Reactive sintering using... 

---