Doped poly Electroactive polymers

C. Le Hiie, A. Moliton, B. Lucas, and G. Froyer. Compensation phenomena by ion implantation doping of an electroactive polymer, poly(parapheny-lene), Adv. Mater. Opt. Electron. 7 173 (1992). 

Rault-Berthelot J, Angely L, Delaunay J, Simonet J (1987) The polyfluorenes a family of versatile electroactive polymers. (11) Poly(9,9-disubstituted fluorenes) existence of reversible p or n doping. New J Chem 11 487 94... 

The first water-soluble, electroactive, self-doped sulfonatoalkoxy-substituted PPP, poly[2,5-bis(3-sulfonatopropoxy)-l,4-phenylene-aZf-l,4-phenylene] (55), was synthesized from 1,4-benzenediboronic acid [4612-26-4] (56) and the disodium salt of l,4-dibromo-2,5-bis(3-sulfonatopropoxy)benzene (57) by the homogeneous Suzuki coupling method (130). The polymer purified by dialysis of an aqueous solution was composed exclusively of 1,4-linkages. The abihty to utilize a variety of bis(boronic acids) in this polymerization with sulfonate containing aiyl hahdes will lead to a high degree of structural control of the optoelectronic properties of these water-soluble poljnners. 

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