DL-Glucitol

N,N,N, N -Tetra-Me 2,5-Anhydro-l, 6-dideoxy-l,6-bis (dimethy lamino)-DL-glucitol [84379-94-2]... 

DL-Glucitol (DL-gulitol) has been made by mixing equimolar quantities of the two components and has also been isolated in small yield from a commercial sorbitol prepared by the electrolytic reduction of D-glucose under alkaline conditions (38). 

The competitive inhibition of aldolase by a number of structural analogs of D-ftuctose 1,6-diphosphate has been investigated.120 Among these analogs were 1,4-anhydro-DL-ribitol 5-phosphate, 1,4-anhydro-DL-xylitol 5-phosphate, 1,4-anhydro-D-arabinitol 5-phosphate, 2,5-anhydro-D-mannitol 1,6-diphosphate, and 2,5-anhydro-D-glucitol 1,6-diphosphate. Their respective, enzyme-inhibitor,... 

Five 1,1-dl-C-substltuted 1-deoxy-D-rlbitol derivatives, including compounds (42) and (43), and two 1-deoxy-D-glucitol analogues have been synthesized by condensation of aldehydo-sugar derivatives with 3-methyl-l-phenyl-5-pyrazolone and shown to have... 

DIAN. See Bisphenol A Dianal. See Acrylic resin 1,4 3,6-Dianhydro-2,5-di-0-methyl-D-glucitol. See Dimethyl isosorbide 1,4 3,6-Dianhydro-D-glucitol monolaurate. See Isosorbide laurate (Z)-Dianhydro-D-mannitol, mono-9-octadecenoate Dianhydromannitol monooleate D-Dianhydromannitol monooleate. See Mannide monooleate 1,4 3,6-Dianhydrosorbitol 2,5-dinitrate. See Isosorbide dinitrate 1,2 3,4-Dianhydro-DL-threitol. See DL-Diepoxybutane p,p -Dianiline. See Benzidine 1,4-Dianilinobenzene. See N,N -Diphenyl-p-phenylenediamine... 

Diamino-1,6-dideoxy-2,3,4,5-tetra-0 -methyl-i>mannit ol, D-448 2,3 4,5-Dianhydroallitol, D- 2 2,5 3,4-Dianhydroaltritol D-form, D-489 2,5 3,4-Dianhydroaltritol L-form, D-489 2,5 3,4-Dianhydroaltritol DL-/orm, D-489 l,2 4,5-Dianhydro-3-0-benzoylxylitol, D-516 l,4 3,6-Dianhydro-5-0-benzyl-D-glucitol, D-503 2,5 3,6-Dianhydro-l-deoxyglucitol D-form, D-492 2,5 3,6-Dianhydro-l-deoxy-4-0-mesyl-D-glucitol, D-492 2,5 3,6-Dianhydro-l-deoxy-4-0-tosyl-D-glucitol, D-492 2,5 3,4-Dianhydro-l,6-di-0-benzoyl-D-altritol, D-489 l,4 3,6-Dianhydro-2,5-di-0-benzoyl-D-iditol, D-507 l,4 3,6-Dianhydro-2,5-di-0-benzoyl-L-iditol, D-507 l,4 3,6-Dianhydro-2,5-di-0-benzoyl-DL-iditol, D-507 2,3 4,5-Dianhydro-l,6-di-0-benzoyl-D-iditol, D-662... 

Branched-chain di-C-methylpentltol derivatives (10) with the L-xylo-, L-rlbo, D-lyxo, and D-arabino-configuratlon, required for the synthesis of polyketlde-derlved natural products, have all been synthesized from the exo-methylene derivative (11). Photochemical addition of cyclohexene to aldehydo-D-glucose penta-acetate gave the 8-(pentltol-1-yl)-7-oxabicyclo[4.2.Oloctane derivative (12) in 65% yield.The 1,1-dl-C-substltuted-l-deoxy-D-glucitol derivative (13) was the major product from acid-catalysed... 

Procedures have been described for synthesizing l,4 3,6-di-anhydro-hexitols from D-glucitol and D-mannitol,and for 1,4-anhydro-DL-xylitol from D-xylitol,under acid-catalysed... 

---