Dithiocarbimic acid metal complexes

Dithiobenzoic acid metal complexes, 2, 646 colours, 2, 646 Dithiobiuret metal complexes, 2, 640 Dithiocarbamates chelating resins mineral processing, 6,826 Dithiocarbamic acid metal complexes, 2,585 amine exchange, 1,428 photographic emulsions, 6,98 nickel poisoning, 6,768 tellurium(Il) complexes photothermography, 6,121 Dithiocarbazic acid metal complexes, 2,803 Dithiocarbimic acid metal complexes, 2,588 Dithiocarbimic acid, cyano-metal complexes, 2,808 Dithiocarboxylic acids metal complexes, 2,646 Dithiodiacetic acid metal complexes, 2, 806 Dithiodiketones... 

Dithiocarbamic acid itself and its alkali metal salts are unstable towards hydrolysis but metal chelates are known and a structure of [Co(S,CNH2)3] is available (Table 96). This complex is probably unstable towards hydrolysis giving [Co(S2CO)3]3. Salts of dithiocarbamates derived from primary amines are also unstable under alkaline conditions, although N(3)-substituted dithiocar-bazic acid forms green tris(S,S) chelates (336).1133 The similar N(3)-unsubstituted acids form (N,S) chelates (337) which can be deprotonated when R = H with possible isomerization to the (S,S) dithiocarbimate chelate (339).1133 The (N,S) chelate (338) has been positively identified by a crystal structure of its 5-methyl ester, R = H (Table 96).1134... 

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See also in sourсe #XX -- [ , ]

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