Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Disulfido

Disiloxane, tetramesityl-, 3,206 Disproportionation iridium catalysts, 4,1159 Dissolution nuclear fuels, 6, 927 Distannene, 3,217 Distannoxane, 1,3-dichloro-, 3,207 Distibine, tetraphenyl-, 2,1008 Distibines, 2,1008 Disulfido ligands metal complexes, 2,531-540, 553 bonding, 2, 539 electron transfer, 2, 537 intramolecular redox reactions, 2,537 reactions, 2, 537... [Pg.123]

Scheme 6 Synthesis of platinum disulfido complexes from zerovalent platinum complexes... Scheme 6 Synthesis of platinum disulfido complexes from zerovalent platinum complexes...
Scheme 18 Synthesis of group 5 metal disulfido complexes from the metal thiolato complexes... Scheme 18 Synthesis of group 5 metal disulfido complexes from the metal thiolato complexes...
Scheme 24 Synthesis of group 6 metal disulfido complexes... Scheme 24 Synthesis of group 6 metal disulfido complexes...
Scheme 31 Synthesis of ruthenium and rhenium disulfido complexes by the use of (TMS)2S as a sulfur reagent... Scheme 31 Synthesis of ruthenium and rhenium disulfido complexes by the use of (TMS)2S as a sulfur reagent...
The insertion reaction of dimethyl acetylenedicarboxylate (DMAD) into the S-S bond of a cyclic disulfido complex of niobium, Nb(S2)(S2CNEt2)3, takes place to give the corresponding dithiolene complex, Nb S2C2(C02Me)2 (S2CNEt2)3 (Scheme 56) [134]. [Pg.190]

Scheme 56 Reaction of niobium and molybdenum disulfido complexes with alkyne... Scheme 56 Reaction of niobium and molybdenum disulfido complexes with alkyne...
The dinuclear rhenium disulfido complex with n,rj -S2 ligands (ReCp )2(/U-S2)2 (Cp =7j -C5Me4Et) (type IIa2 complex in Fig. 2) undergoes an insertion reaction of acetylene and ethylene into the S-S bond according to Scheme 57. [Pg.190]

Scheme 59 Reaction of diruthenium disulfido complexes with 1,3-dienes... Scheme 59 Reaction of diruthenium disulfido complexes with 1,3-dienes...
Scheme 60 Reaction of a diruthenium disulfido complex with olefins... Scheme 60 Reaction of a diruthenium disulfido complex with olefins...
Scheme 61 Plausible mechanism for the reaction of diruthenium disulfido complexes with olefins... Scheme 61 Plausible mechanism for the reaction of diruthenium disulfido complexes with olefins...
The oxidation of [Cr(SH)(H20)5]2+ by I2 or Fe3+ under aerobic conditions in acid solutions gives the disulfido-bridged complexes [(H20)5CrS2Cr(H20)5]4+ and [(H20)sCr(S2H)Fe-(H20)5]4+ respectively (Scheme 100).967,968 The latter complex can also be obtained by substitution of chromium(III) in the former complex by iron(II) under acid conditions. The product distribution in the iron(UI) oxidation of [Cr(SH)(H20)5]2+ is pH dependent and at 298 K, pH = 1 the heteronuclear dimer [(H20)5Cr(S2H)Fe(H20)5]4+ constitutes over 80% of the product mixture. The rate of this reaction shows a [H+] 1 dependence, an observation consistent with [CrS(H20)5]+ being the kinetically active species. [Pg.882]

See other pages where Disulfido is mentioned: [Pg.215]    [Pg.222]    [Pg.115]    [Pg.670]    [Pg.104]    [Pg.167]    [Pg.168]    [Pg.160]    [Pg.164]    [Pg.164]    [Pg.174]    [Pg.174]    [Pg.175]    [Pg.175]    [Pg.177]    [Pg.184]    [Pg.184]    [Pg.185]    [Pg.188]    [Pg.190]    [Pg.191]    [Pg.192]    [Pg.193]    [Pg.195]    [Pg.91]    [Pg.462]    [Pg.484]    [Pg.491]    [Pg.109]    [Pg.109]    [Pg.109]    [Pg.61]    [Pg.139]    [Pg.876]   
See also in sourсe #XX -- [ Pg.876 ]

See also in sourсe #XX -- [ Pg.3 , Pg.876 ]



SEARCH



Dimeric disulfido

Disulfido complexes

Disulfido ligands

Disulfido ligands bonding

Disulfido ligands metal complexes

Disulfido ligands reactions

Heptacarbonyl(disulfido)dimanganese(I)

Metal-disulfido complex

Molybdenum complexes disulfido

© 2024 chempedia.info