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Distribution functions uniform

The larger the value of n, the more uniform is the size distribution. Other types of distribution functions can be found in Reference 1. Distribution functions based on two parameters sometimes do not accurately match the actual distributions. In these cases a high order polynomial fit, using multiple parameters, must be considered to obtain a better representation of the raw data. [Pg.331]

Boltzmann s H-Theorem. —One of the most striking features of transport theory is seen from the result that, although collisions are completely reversible phenomena (since they are based upon the reversible laws of mechanics), the solutions of the Boltzmann equation depict irreversible phenomena. This effect is most clearly seen from a consideration of Boltzmann s IZ-function, which will be discussed here for a gas in a uniform state (no dependence of the distribution function on position and no external forces) for simplicity. [Pg.17]

Mixing Models. The assumption of perfect or micro-mixing is frequently made for continuous stirred tank reactors and the ensuing reactor model used for design and optimization studies. For well-agitated reactors with moderate reaction rates and for reaction media which are not too viscous, this model is often justified. Micro-mixed reactors are characterized by uniform concentrations throughout the reactor and an exponential residence time distribution function. [Pg.297]

Figure 2. Comparison of the simulated velocity distribution (histogram) with the Maxwell— Boltzmann distribution function (solid line) for kgT —. The system had volume V — 1003 cells of unit length and N = 107 particles with mass m = 1. Rotations (b were selected from the set Q — tt/2, — ti/2 about axes whose directions were chosen uniformly on the surface of a sphere. Figure 2. Comparison of the simulated velocity distribution (histogram) with the Maxwell— Boltzmann distribution function (solid line) for kgT —. The system had volume V — 1003 cells of unit length and N = 107 particles with mass m = 1. Rotations (b were selected from the set Q — tt/2, — ti/2 about axes whose directions were chosen uniformly on the surface of a sphere.
One may also show that MPC dynamics satisfies an H theorem and that any initial velocity distribution will relax to the Maxwell-Boltzmann distribution [11]. Figure 2 shows simulation results for the velocity distribution function that confirm this result. In the simulation, the particles were initially uniformly distributed in the volume and had the same speed v = 1 but different random directions. After a relatively short transient the distribution function adopts the Maxwell-Boltzmann form shown in the figure. [Pg.95]

Dependence of results from the prior-prejudice distribution. Non-uniform prior-prejudice distributions (NUP for short in what follows) were initially introduced by Jauch and Palmer by centering 3D Gaussian functions at the nuclear positions [29]. They found that the low-density regions of the crystal changed significantly upon introduction of the NUP, but the uneven distribution of errors persisted. [Pg.15]

A constant density of correlated random coordinates (x, y) was distributed over nonrectangular areas A by equating the cumulative distribution function of area A, expressed relative to x, to a random number R (0uniformly distributed between its bounds at that x using another random number. [Pg.50]

A further consideration is that the value of the calculated nonlinearity will depend not only on the function that fits the data, we suspect that it will also depend on the distribution of the data along the X-axis. Therefore, for pedagogical purposes, here we will consider the situation for two common data distributions the uniform distribution and the Normal (Gaussian) distribution. [Pg.453]

For investigation of the effect of the width, w, of the distribution on the ultimate fibre strength the uniform chain distribution function is chosen. As in experiments often only the molecular weight distribution fw(z)=zfi(z)z l is determined, we used a uniform molecular weight distribution with a width w defined as... [Pg.69]

Due to the particular mechanism of these reactions, the macromolecules so formed have varying degrees of polymerisation. Even natural polymer compounds except certain proteins are not uniform with respect to their Molecular weight. Because of this reason, any polymer sample has a characteristic Molecular weight distribution (MWD), which can be represented by a distribution function or a distribution curve. [Pg.62]

A polymer is the more uniform with respect to the molecular weight the steeper the integral distribution curve is. The differential mass distribution function... [Pg.116]

Equation (1.15) has been integrated numerically on a logarithmic scale to determine the dummy variable The logarithmic scale weighs more uniformly the relaxation times, which may cover several orders of magnitude. A change of variables, y = n (k = ln(T g/T ), transformed the distribution function given by... [Pg.23]

Rahaman and Hatton [152] developed a thermodynamic model for the prediction of the sizes of the protein filled and unfilled RMs as a function of system parameters such as ionic strength, protein charge, and size, Wq and protein concentration for both phase transfer and injection techniques. The important assumptions considered include (i) reverse micellar population is bidisperse, (ii) charge distribution is uniform, (iii) electrostatic interactions within a micelle and between a protein and micellar interface are represented by nonlinear Poisson-Boltzmann equation, (iv) the equilibrium micellar radii are assumed to be those that minimize the system free energy, and (v) water transferred between the two phases is too small to change chemical potential. [Pg.151]

This rotation modifies the orientational distribution function f(a t) to f(a t) + 8f(a t) through Eq. (39) with Eq. (40b), the last term on the right hand side dominating over the others if the deformation is very rapid or the time 8t is very short. The argument r in f(r,a t) is omitted because we are concerned only with uniform solutions. [Pg.129]

Exercise. Prove that the characteristic function of any probability distribution is uniformly continuous on the real k-axis. [Pg.7]

Deviations from EVM behaviour at low Cs (high a) values were first described successfully in terms of a non-uniform charge distribution by Glueckauf n2), who postulated the existence of equipotential microregions each characterized by a local concentration of fixed charged groups CFL. It was further postulated that CKL conforms to the following distribution function... [Pg.123]

It is found that as the solute size is increased, keeping all other parameters fixed, the peak in the solute-solvent radial distribution function slowly disappears and approaches the value 1. This implies that the probability of a solvent particle, provided that there is a solute at the origin, is same everywhere. The solute-solvent static structure factor Si2(q), which can be obtained from g 12(f), will also have no structure and will have a uniform value that is, Si2(q) = 1 for all wavenumbers. [Pg.161]

Selecting the points for crossover and mutation according to a probability distribution, either uniform or skewed towards points at which the optimized function takes high values (the latter being a probabilistic expression of the survival-of-the-fittest principle). [Pg.155]


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