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Distinguished coordinate procedure

The best way to determine the type of unit cell adopted by a metal is x-ray diffraction, which gives a characteristic diffraction pattern for each type of unit cell (see Major Technique 3 following his chapter). However, a simpler procedure that can be used to distinguish between close-packed and other structures is to measure the density of the metal we then calculate the densities of the candidate unit cells and decide which structure accounts for the observed density. Density is an intensive property, which means that it does not depend on the size of the sample (Section A). Therefore, it is the same for a unit cell and a bulk sample. Hexagonal and cubic close packing cannot be distinguished in this way, because they have the same coordination numbers and therefore the same densities (for a given element). [Pg.319]

In terms of the quantum-potential formulation particle trajectories can be associated with the quantum HJ equation (6) in exactly the same way as in the classical case [34, 35]. As before, particle trajectories associated with the phase S may be obtained by constructing the normals to S, each one distinguished by its initial coordinates. By this procedure Bohm managed to revive the pilot-wave model of De Broglie. It means that a point particle of mass m on a trajectory x = x(t), is now associated with the physical... [Pg.65]

Here the subscripts on the gradient operators distinguish derivatives with respect to spatial and velocity coordinates, and M is the total number of different kinds of particles (classified according to their chemical composition). The details of the procedure for deriving equation (1) (considering the volume element dr d dy and counting what enters and leaves) are so familiar in fluid dynamics and in kinetic theory that they need not be repeated here. Equation (1) will be called the spray equation. [Pg.450]

Some believe that there are two main template effects kinetic and thermodynamic [8]. The latter is responsible for an increase in the yield of the complex with ligands formed in situ in the presence of metal ions, which bind products that result from ordinary reactions and to withdraw them from the reaction medium. These procedures are not true template reactions since they do not satisfy the above-mentioned conditions, and the metal ion causes equilibrium shift only. It is impossible to distinguish between kinetic and thermodynamic contributions to the template effect, since the coordination to the metal ion simultaneously causes both steric... [Pg.249]

In order to improve the accuracy of the BFBT results, as well as to determine reliable coordination numbers, a newly developed fine adjustment procedure (42) was applied to the best-fit results (FABM fine adjustment based upon model). This technique helps to alleviate parameter correlation problems and provides a simple graphical technique to distinguish a good "model" from a "bad" model. A "good" model has been operationally defined as one which has parameters and parameter correlation... [Pg.249]

For complexes containing solvent ligands that are both poorly coordinating and volatile, this procedure may be carried out at room temperature or even lower temperatures using vacuum line techniques. Such procedures are particularly useful for complexes that are thermally unstable toward isomerization or other chemical processes. Coordinated and ionic trifluoromethanesulfonate can usually be distinguished by infrared spectroscopy. ... [Pg.249]

We shall consider here a population of particles distinguished from one another by a finite dimensional vector x of internal coordinates and distributed uniformly in space. Further, we shall be concerned with the open system of Section 2.8 whose behavior is dictated by the population balance equation (2.8.3). Thus the number density in the feed,/i jn(x), may be assumed to be Nff x) where Nf is the total number density in the feed stream and /(x) is probability density of particle states in it. It will also be assumed that the continuous phase plays no role in the behavior of the system. Relaxing this assumption does not add to any conceptual difficulty, although it may increase the computational burden of the resulting simulation procedure. [Pg.173]

What distinguishes a micro injection process from a normal injection molding process Except for parts or structure sizes, the process is almost identical. Often, even the same procedures are applied, both In the actual injection molding process as well as in the manufacture of the molds. Several studies (NEXUS Task Eorce Market Analysis) also point out the current potential as well as future developments. The entire process is very important in microinjection molding. Therefore, the process is also often referred to microsystems technology (MST). The coordination of the process includes ... [Pg.284]


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Coordination procedure

Distinguishable

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