Diphenyl complex with

PtPh2(SMe2)2 reacts with (2-ClC6H4)GH=NGH2GH2NMe2 to produce a monophenylplatinum complex having a 6, iV,7V-tridentate ligand (659, Equation (139)). An intermediate diphenyl complex with the bidentate ligand 658... 

Radical cyclization to triple bonds is used as the key step for the synthesis of oxygen heterocycles. This methodology can benefit from a Lewis acid, such as aluminum fns(2,6-diphenyl phenoxide) (ATPH), which forms a complex with the... 

Suga and Ibata [44] prepared binaphtyldiimine derivatives 36 (Scheme 19) affording 98% ee as best selectivity for the transformation of 1,1-diphenyl-ethylene with Z-menthyl diazoacetate. The authors performed PM3 calculations and proposed an optimized structure of the copper complex to explain the high enantioselectivity observed with 1,1-disubstituted olefins. 

A stopped flow technique coupled with spectrophotometric analysis of the iron (II) complex formed has been used to investigate - the reactions of some organic complexes of iron(III) with the ion Fe ". The iron(III) was complexed with 1,10-phenanthroline, various substituted 1,10-phenanthrolines (5-methyl-, 5-nitro-, 5-chloro-, 5-phenyl-, 5,6-dimethyl-, 4,7-diphenyl-, and 3,4,7,8-tetramethyl-) and 2,2 -dipyridine, 4,4 -dimethyl-2,2 -dipyridine, and 2,2, 2"-tripyridine. The wavelengths used for the analysis lay in the region 500-552 m/i. 

A review10 with eight references describes the photochemical reactions of the binuclear palladium(0) complex [Pd2(dppm)3] (dppm = bis(diphenyl)phosphinomethane) with organic halides. 

The zinc complexes with diphenyl-2-pyridylmethane, ZnL2Cl2 and ZnL2Br2, have been characterized by IR spectroscopy and conductivity measurements.107 The [(pyridyl)2P(NSi Mc3)2] ligand forms an aminoiminophosphoranate complex with zinc which structural characterization shows to be four-coordinate bound to two pyridyl and two amide nitrogen donors (3).108... 

Bloodworth, A. J., et al., J. Chem. Soc., Perkin Trans. 1, 1983, 471-473 Attempted thermal dehydration of benzeneseleninic acid, formed by oxidation of diphenyl diselenide with hydrogen peroxide, gave a solid which exploded at 53-55°C. The solid may have been the complex of the acid with hydrogen peroxide. 

Iridium(III) hydride forms complexes with DIOP, BDPP (2,4-bis(diphenyl-phosphino)pentane), NORPHOS, and BINAP ligands to produce amines in 11 -80% ee.679 Similar modest results are obtained in the reduction of N-arylketimines with an iridium(HI) complex with (2S,3 S) -C HIRA PHOS as the chiral ligand.680 The indium complexes with chiral phosphinodihydrooxazoles catalyze the enantioselective hydrogenation of imines in supercritical carbon dioxide with up to 80% ee, but generally lower ee values are observed in... 

More recently, the El and electrospray ionization (ESI) mass spectra of 2,5-diaryl- and 2-arylamino-5-aryl-l,3,4-oxadiazoles, as well as their complexes with copper cations, were studied. Under ESI conditions, loss of NH3 and HNCO, from complexes of 2,5-diphenyl-l,3,4-oxadiazole, 2,5-bis(2-pyridyl)-l,3,4-oxadiazole, or 2,5-bis(4-pyridyl)-1,3,4-oxadiazole with copper cation, was observed <2004JMP272>. An unusual elimination of isocyanic acid was found in fragmentation of some protonated 2,5-diaryl derivatives <2002RCM390>. 

An excess of l-chloro-3-iodopropane must be employed to compete effectively with the diphenyl sulfide for complexation with silver fluoroborate. 

A rather complex mixture of products is obtained from the reaction of benzyl-idenetriphenylphosphorane and CS2.48 The major product from the reaction of diphenyl disulphide with methylenetriphenylphosphorane is tris(phenylthio)-methane (44) and only a trace of the insertion product bis(phenylthio)methane is isolated.49 Presumably the salt (45) is deprotonated before it can react with the phenylthioate anion (Scheme 12). a-Thiocarbonyl-stabilized ylides (46) are obtained from the reaction of ylides with S-alkyl thiolcarboxylates.50... 

The square-planar geometry (with slight tetrahedral distortion) of these derivatives can be proved by that of the related Rh(I) complex with 2,2/-bis [o-(diphenylphosphine)benzylidene]amine -6,6/-dimethyl-diphenyl, [Rh(PPNN)]+, Figure 23.26... 

Two five-coordinate Mn =0 complexes with N2O2 tetradentate ligands Ph4P[MnOL] (L= 1,2-bis(2-methyl-2-oxypropanamido)benzene and 1,2-bis(2,2-diphenyl-2-hydroxyethanamido)benzene) have been prepared and structurally characterized (12) and (13), respectively.These complexes and the 0x0 complexes discussed in the next section may have utility in oxo-transfer reactions to organic substrates such as olefins and ethers. 

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