Dilatometric

Relaxations of a-PVDF have been investigated by various methods including dielectric, dynamic mechanical, nmr, dilatometric, and piezoelectric and reviewed (3). Significant relaxation ranges are seen in the loss-modulus curve of the dynamic mechanical spectmm for a-PVDF at about 100°C (a ), 50°C (a ), —38° C (P), and —70° C (y). PVDF relaxation temperatures are rather complex because the behavior of PVDF varies with thermal or mechanical history and with the testing methodology (131). 

Glass-transition temperatures are commonly determined by differential scanning calorimetry or dynamic mechanical analysis. Many reported values have been measured by dilatometric methods however, methods based on the torsional pendulum, strain gauge, and refractivity also give results which are ia good agreement. Vicat temperature and britde poiat yield only approximate transition temperature values but are useful because of the simplicity of measurement. The reported T values for a large number of polymers may be found ia References 5, 6, 12, and 13. 

High-resolution dilatometric measurements have revealed the appearance of anisotropy in the cubic-phase thermal strain in the precursive temperature region for the soft-mode martensitic transformations in VaSi/ Ni-Al, In-Tl/ and SrTiOa In the case of Ni-Al and SiTiOa, the onset temperatures for the strain anisotropy are close to those at which the appearance of central peak behaviour occurs. 

Using data obtained from thermocurrent, piezoelectric and dilatometric measurements, the first and second pyroelectric coefficients were calculated for the Rb5Nb3OFi8 crystal. Fig. 114 presents the results. 

Die Tg can be determined readily only by observing the temperature at which a significant change takes place in a specific electric, mechanical, or physical property. Moreover, the observed temperature can vary significantly, depending on the specific property chosen for observation and on details of the experimental technique (for example, the rate of heating, or frequency). Therefore, the observed Tg should be considered to be only an estimate. The most reliable estimates are normally obtained from the loss peak observed in dynamic mechanical tests or from dilatometric data (ASTM D-20). 

Sample dilatometric data are given in Table 2-3. Figure 2-4 shows the variation of V, the dilatometer reading, with time, and the line represents the least-squares fit to Eq. f2-30). 

Some typical examples of this autoacceleration are (Figure 5) Norrish and Smith ( 2) polymerized methyl methacrylate in bulk and in the presence of various precipitants and measured the polymerization rates dilatometrically. They determined that autoacceleration of the precipitation polymerizations was larger than that observed for the Trommsdorf effect in bulk polymerization. 

Couman W.J., Heikens D., and Sjoerdsma S.D., Dilatometric investigation of deformation mechanism in polystyrene-polyethylene block copolymer blend Correlation between Poisson ratio and adhesion. 

The reduction by Cu(I) in acetonitrile at 110 °C in the presence of styrene was followed dilatometrically The mechanism given is... 

The melting transition in polymers is conveniently observed by dilatometric measurements of the volume as a function of the temperature. Results thus obtained for poly-(N,N -sebacoyl piperazine) are shown in Fig. 129, and for poly-(decamethylene adipate) by the lowest curve in Fig. 130. Most of the melting, as evidenced by the abnormal increase in volume, occurs within a range of 10°, and it terminates abruptly at a temperature which may be defined within 0.5°. The data shown were obtained by raising the temperature... 

Begala, A. J. Strauss, U. P. (1972). Dilatometric studies of counterion binding by polycarboxylates. Journal of Physical Chemistry, 76, 254-60. 

DD can be monitored by a variety of experimental techniques. They involve thermodynamic, dilatometric, and spectroscopic procedures. Molecular dynamics (MD) simulations also become applicable to self-assembled systems to some extent see the review in Ref. 2. Spectroscopic methods provide us with molecular parameters, as compared with thermodynamic ones on the macroscopic level. The fluorescence probing method is very sensitive (pM to nM M = moldm ) and informs us of the molecular environment around the probes. However, fluorescent molecules are a kind of drug and the membrane... 

Dilanacin, molecular formula and structure, 5 98t Dilantin, folic acid and, 25 803 Dilatancy, 21 717 Dilatant flow, 7 280t 8 728 Dilatant fluids, 11 768, 769 Dilatometers, vitreous silica in, 22 441 Dilatometric techniques, 13 436... 

A summary of the results (calorimetric and dilatometric) is given in Table 1. 

Figure 1 First-order plots of typical calorimetric and dilatometric experiments...

In the calorimetric studies, the kinetic acceleration only became apparent when the calorimeter was stabilised to a constant temperature, rather than to a constant pre-cooling rate as had been the practice in the earlier work this improvement in technique had revealed the acceleration. However, the acceleration and the corresponding increase in conductivity were also observed in the isothermal dilatometric studies so that they cannot have been caused simply by the increase in temperature during the adiabatic reactions in the calorimeter. As is well-known [la] with this system, the degree of polymerisation of the polymer increases slightly as the concentration of the initiator is lowered (Table 1). 

A. One Atmosphere Densities. The densities or volume properties of solutions have been studied by a number of methods which are extensively reviewed elsewhere (4,5. 6,7) of all of the methods, only the magnetic float (7-14), the hydrostatic balance (3,15-20), the vibrating flow densimeter (21,22), and dilatometric (23,24,25) methods give data with sufficient precision to study the densities of dilute solutions. For more concentrated... 

Surface tension and density of liquid alloys have been studied by Moser et al. (2006). Measurements by maximum bubble pressure and dilatometric techniques were carried out in an extensive range of temperatures on liquid alloys close to the ternary eutectic Sn3 3Ag0 76Cu with different Sb additions, which decrease surface tension and density. The experimental data were discussed in comparison also with values calculated on the basis of different models. 

The reactions are accompanied by a considerable volume change, and a dilatometric method was employed by Bell and Higginson (1949), who added acetaldehyde-water mixtures (containing about equal quantities of MeCHO and MeCH(OH)2) to an excess of acetone, and thus measured kj, in presence of a large number of acid catalysts. The direct hydration of acetaldehyde in aqueous buffer solutions is inconveniently fast at room temperatures, but ( (j + A ) was measured dilatometrically at 0°C by Bell and Darwent (1950), who established the existence of general acid-base catalysis. 

The direct evidence that Besenhard et al. presented for the formation of a ternary GIC is the dilatometric measurement of the graphite electrode, which indicates a crystal expansion of 150% at the cointercalation potential. However, this expansion due to solvent cointercalation was never confirmed on the microscopic level. All of the in situ X-ray diffraction (XRD) measurements conducted by different research-... 

PLASTOFROST PLASTIC RANGE ( C) Figure 7. Cross plot of dilatometric and Plasto ost plastic ranges. 

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