1.3- Dihalides mixed

The mixed halide-hydrides PhjSnHCl and PhjSnHBr have been prepared from the reaction of diphenyltin dihydride with the appropriate diphenyltin dihalides (274). 

This type is produced from a mixed dihalide, di-2-chloroethyl formal and ethylene dichloride, and sodium polysulphide. A high molecular weight polymer, ca. 100,000, is produced with predominantly hydroxyl end groups on the polymer chain. The sulphur content of the resultant polymer is 49%. 

Recently, the first structural characterization of mixed sulfur selenium dihalides, SeSX2 (X = Br, Cl), has been reported in mixtures of S2C12 and Se2X2 (X = Br, Cl).29,30 In addition, two-dimensional NMR exchange... 

Halogen exchange reactions can also be used for the preparation of mixed diorganotin dihalides of the type R2SnXY337 (X, Y = Cl, Br, I) ... 

Cyclic 1,3-diketones have been converted into / -halogeno-ketones (118) by tri-phenylphosphine dihalides in benzene or acetonitrile,100 although this paper adds little to previous work101 in this field. The reactions of phosphorus pentachloride with acetals have been extended to mixed acetals, such as (119).102 Only one product... 

With sodium sulphide hydrate (general procedure) The diorganyltellurium dihalide is mixed with a 15 times molar excess of Na2S 9H2O and the mixture heated at 95-100°C for 10 min or more, until aU the solid has melted. Sufficient HjO is added to dissolve the sulphide and then the mixture is filtered if the obtained telluride is a solid, or extracted with a solvent (ether or petroleum ether) if the telluride is a liquid. The products are purified by crystallization or distillation. Yields are high or quantitative (except for diphenyl telluride or di-p-tolyl telluride). 

Halides, 7 1-26 actinide elements, 2 195-233 anion dependence, 39 139 berkelium, 28 48, 51-53 beryllium, 14 255-332 binary, 35 237-246, 274-280 decomposition, 35 277 dichalcogen dihalides, 35 279-280 equilibrium studies, 35 242 mixed-ligand halides, 35 244-246 reactions, 35 246 selenium halides, 35 240-241... 

A mechanism that accounts for the oxidative addition of halocarbons has been proposed for the two d8-d8 dimers (Figure 4) (23). The mechanism involves the oxidative quenching of the triplet excited state of the metal dimer as the primary photoprocess. This gives a radical anion species that dissociates a halide, thereby producing an organic radical. The dissociated halide adds to the partially oxidized metal dimer to form a mixed valence Ir -Ir -X or Pt 1-Pt -X intermediate. This intermediate reacts further with the remaining organic radical (presumably in a second, thermal electron transfer step) to form the final d2-d2 dihalide dimer. 

Another type of divalent organotin n complex has been reported by Noltes et al. (228,229). The cyclopentadienyltin halides LXIXa,b precipitate upon mixing concentrated THF solutions of stannocene with the tin dihalides [Eq. (38)]. The complex LXIXa can also be obtained by the reaction of LXVIIIa with hydrogen chloride in THF [Eq. (39)] (228). Similarly, the pentamethylcyclopentadienyltin compounds LXIXc,d have been prepared from decamethylstannocene LXVIIIc and the appropriate carboxylic acid [Eq. (40)] (230). 

Reaction of Diorgano Tellurium Dihalides with Sodium Sulfide General Procedure A 15-fold molar excess of sodium sulfide nonahydrate is mixed with the diorgano tellurium di halide and the mixture is heated at 90-95° on a boiling water bath. When the mixture has become liquid, it is stirred for an additional 10 min. and then cooled. Water is added to dissolve the sulfide and the mixture is filtered to collect the solid diorgano tellurium product. Liquid diorgano tellurium products are extracted into petroleum ether. Products are purified by recrystallization or distillation. 

The reaction of bis[trifluoromethyl] tellurium with chlorine fluoride at — 78° with fluorotrichloromethane as solvent first produced his[trifluoromethyl] tellurium chloride fluoride. When the reaction mixture was concentrated, the l9F-NMR signal of the chloride fluoride disappeared and was replaced by signals for bis[trifluoromethyl] tellurium difluoride and bis[trifluoromethyl] tellurium dichloride2. The diorgano tellurium dihalides reported in the literature as mixed dihalides might be mixtures of symmetrical dihalides. All mixed halide species were identified by 125Te- and 19F-NMR spectroscopy in dimethylformamide solutions prepared from equimolar amounts of two different tellurium dihalides3. 

According to conductivity measurements, the aqueous ethanolic solutions obtained by mixing equimolar amounts of dialkyl tellurium dihalides and dihydroxides contain dialkyl tellurium hydroxide halides2,3. 

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