Diglucoside

Lauryl diglucoside is used in shampoos as a detergent and as a thickening agent. 

The pKj, value (2.43) of the hydration constant of the cyanidin was found to be lower than the pKj, values of glycosylated and acylated cyanidins, meaning lower resistance of the anthocyanidin to hydration. The stability of nonacylated 3,5-diglucosides was lower compared to the 3-glucoside because the 5 position markedly lowered the hydration constant due to decreased electron density of the pyrilium ring that favors nucleophilic attack by water, enhancing hemiacetal formation. ... 

Stability of anthocyanins can be attained by self-association, that is, when two or more anthocyanin molecules are associated. This effect was verihed by increasing the concentration of the cyanidin 3,5-diglucoside solution from 10 M to 10 M with a consequent bathochromic shift in maximum wavelength absorption in the visible region. "... 

Members of the family Amaranthaceae are known to produce ecdysteroids such as 8-ecdysone (19) and inocosterone (20). From petroleum ether extracts of Amaranthus splnosus Linn. Behari and Andhiwal (21) obtained 8-sitosterol (4), stigmasterol (3), campesterol and cholesterol. From the roots of the same species, Banerji (22) isolated two new saponins, a diglucoside and a triglucoside of o-spinasterol. More recently, Roy et al. (23)... 

A selective 6-acetylation of the following diglucoside in 71% yield by JV-acetyl-imidazole has been reported [200]... 

Figure 5.13 GALDI mass spectrum of aloe resin (from THF solution). The two doublets correspond to mono and diglucosides of aloe emodin and their oxidation and reduction products, respectively (see Table 5.5)...

Silk dyed with Reseda luteola, Sophora japonica and Allium cepa Rutin, quercetin, kaempferol, kaempferol 3,7 diglucoside, quercetin 4 glucoside, luteolin HCI/Me0H/H20, HCOOH/MeOH, H2EDTA/ACN/MeOH A H20 B ACN C H20 with HCOOH 350, 450, 490 nm/ ESI( ) Column C4 6... 

Greek saffron Picrocrocin, safranal, crocins, kaempferol diglucoside Me0H/H20 A MeOH B H20 with AcOH 250, 308, 440 nm/ ESI (+) ESI interface 22... 

Fig. 2.7.2. (—)-LC-ESI-MS chromatograms of a standard APG solution, (a) Total ion current trace fromm/2 200 to 600. (b)XIC of Cg-, C10-, and Ci2-monoglucoside, and (c) XIC of Cg-, C10-, and Ci2-diglucoside. Peak numbering as in Table 2.7.1 indices a and b denote different stereoisomeric forms. (Separation on a RP-Cg column with a water/acetonitrile gradient) (Reprinted from [1],...

Ion masses (m/z) of different molecular and adduct ions of alkyl mono- and diglucosides (as assigned in Figs. 2.7.2 and 2.7.5) (Reprinted from [1], Copyright 1999, with permission from Elsevier)... 

Fig. 2.7.7. Stabilisation of charge in sodiated alkyl diglucoside (from [4] with permission...

A rapid technique for the identification of surfactants in consumer products by ESI-MS was proposed by Ogura and co-workers [6], After a simple preparation procedure, infusion of the sample, which was prepared in a water/methanol mixture (50 50) containing 10 mM ammonium acetate, allowed assignment of the [M + NH4]+ ions of Cio- and Ci2-mono- and -diglucoside in the mass spectrum (ion masses as in Table 2.7.1). The approach even permitted quantitative analysis when deuterated internal standards were used. 

Fig. 2.52. HPLC analysis of (a) a methanol extract, (b) a methanol-water extract and (c) a water extract. (A) Luteolin-3 7-diglucoside (B) luteolin-7-glucoside (C) luteolin. Reprinted with permission from D. Cristea et al. [154],...

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