Diethyl-neryl

Allylic phosphates are used for carbonylation in the presence of amines under pressure. Carbonylation of diethyl neryl phosphate (389) affords ethyl homonerate (390), maintaining the geometric integrity of the double bond[244]. The carbonylation of allyl phosphate in the presence of the imine 392 affords the /3-lactam 393. The reaction may be explained by the formation of the ketene 391 from the acyl phosphate, and its stereoselective (2 + 2] cycloaddition to the imine 392 to give the /3-lactam 393(247],... 

The cyclization of polyolefin terpenes occurs readily once they have been converted into terminal epoxides. The tetracyclic diterpenes 3a- and 3/S-kaurene have been prepared enzymically from chemically synthesized (/ ,5)-14,15-oxidogeranylgeranyl pyrophosphate (42), providing another example of this cyclization. Trimethyl-aluminium can promote the non-enzymic cyclization of the diethyl ester of neryl phosphate (43), presumably a carbonium ion, to 4-t-butyI-l-methylcyclohexene. ... 

Geraniol/Nerol N,N-Diethyl-o-geranyl (neryl)-hydroxylamine University of New Castle... 

Neryl diethyl phosphate, 471 Nickel(II) acetylacetonate, 42, 84 Nickel carbonyl, 515 Nickel chloride, 291 Nickel peroxide, 357-358 Nitrene, 250 Nitrile oxides, 464,465 Nitrules, 166, 228, 256, 409,415, 416, 504... 

Formic acid methyl ester. See Methyl formate Formic acid 1-methyl-1-(4-methyl-cyclohex-3-enyl) ethyl ester. See Terpinyl formate Formic acid, neryl ester. See Neryl formate Formic acid octyl ester. See Octyl formate Formic acid, oxydi-, diethyl ester. See Diethyl pyrocarbonate... 

D-(-)-diethyl- or L-(+)-diethyl tartrates as chiral adjuvants. Treatment of the neryl epoxide (150) with titanium tetraisoprop-... 

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