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Density general trend

As in previous theoretical studies of the bulk dispersions of hard spheres we observe in Fig. 1(a) that the PMF exhibits oscillations that develop with increasing solvent density. The phase of the oscillations shifts to smaller intercolloidal separations with augmenting solvent density. Depletion-type attraction is observed close to the contact of two colloids. The structural barrier in the PMF for solvent-separated colloids, at the solvent densities in question, is not at cr /2 but at a larger distance between colloids. These general trends are well known in the theory of colloidal systems and do not require additional comments. [Pg.311]

Following the general trend of looldng for a molecular description of the properties of matter, self-diffusion in liquids has become a key quantity for interpretation and modeling of transport in liquids [5]. Self-diffusion coefficients can be combined with other data, such as viscosities, electrical conductivities, densities, etc., in order to evaluate and improve solvodynamic models such as the Stokes-Einstein type [6-9]. From temperature-dependent measurements, activation energies can be calculated by the Arrhenius or the Vogel-Tamman-Fulcher equation (VTF), in order to evaluate models that treat the diffusion process similarly to diffusion in the solid state with jump or hole models [1, 2, 7]. [Pg.164]

To get an idea of the general trend of dissociation in a gas, we shall consider the isopiestics which represent, at various constant pressures, the density A as a function of temperature. [Pg.351]

Luft and Tsuo have presented a qualitative summary of the effects of various plasma parameters on the properties of the deposited a-Si H [6]. These generalized trends are very useful in designing deposition systems. It should be borne in mind, however, that for each individual deposition system the optimum conditions for obtaining device quality material have to be determined by empirical fine tuning. The most important external controls that are available for tuning the deposition processs are the power (or power density), the total pressure, the gas flow(s), and the substrate temperature. In the following the effects of each parameter on material properties will be discussed. [Pg.108]

Little is known about the variation of the critical stress ", with structure and temperature. For the polyethylene discussed abovedecreased from 620 psi at 22X to 39general trend with all polymers. Turner (84) found that the value of (r(. for polyethylenes increased by a factor of about 5 in going from a polymer with a density of 0.920 to a highly crystalline one with a density of 0.980. Reid (80,81) has suggested that for rigid amorphous polymers. ", should be proportional t° (Tt - T) For brittle polymers, the value of ", may be related to the onset of crazing. [Pg.86]

At the lowest temperatures, the three-body moments are relatively strong, Table 6.4. A density of only 10 amagat will modify the observed moments by roughly 10%. The strong temperature dependence of the three-body moments at low temperature may be quite important for some applications, for example for the spectroscopic modeling of planetary atmospheres. It seems to be related to the formation of dimers and, consequently, to monomer-dimer interactions which are three-body processes by our definition. Of course, at 45 K, quantum corrections are substantial and the numbers quoted must be considered rough estimates. Nevertheless, the general trend of the temperature dependence seems clear. [Pg.297]

The non-linearity of the equations (5.1.2) to (5.1.4) prevents us from the use of analytical methods for calculating the reaction rate. These equations reveal back-coupling of the correlation and concentration dynamics - Fig. 5.1. Unlike equation (4.1.23), the non-linear terms of equations (5.1.2) to (5.1.4) contain the current particle concentrations n (t), n t) due to which the reaction rate K(t) turns out to be concentration-dependent. (In particular, it depends also on initial reactant concentration.) As it is demonstrated below, in the fluctuation-controlled kinetics (treated in the framework of all joint densities) such fundamental steady-state characteristics of the linear theory as a recombination profile and a reaction rate as well as an effective reaction radius are no longer useful. The purpose of this fluctuation-controlled approach is to study the general trends and kinetics peculiarities rather than to calculate more precisely just mentioned actual parameters. [Pg.238]

Fig. 7 also shows a temporal decrease in mass flux in graduated steps. The bound from one step to another is due to the passage of one layer to another in the numerical model and consequently to the decrement of the probability density function of the lift force. This is not directly representative of the reality. However, a general trend of the temporal decrease... [Pg.164]

The known densities of liquid and solid elements at room temperature are shown to the right. Intermolecular forces contribute to density by bringing nuclei closer to each other, so the periodicity is similar to trends for melting point. These group-to-group differences are superimposed on a general trend for density to increase with period number because heavier nuclei make the material denser. [Pg.67]


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