Deluge

If an ethyl ether fire occurs, carbon dioxide, carbon tetrachloride, and dry chemical fire extinguishers meeting National Eire Prevention Association Code 1 and 2 requirements may be used successhiUy (23). Water may also be effectively appHed (see Plant safety). Hose streams played into open tanks of burning ethyl ether serve only to scatter the Hquid and spread the fire. However, ether fires may be extinguished by a high pressure water spray that cools the burning surface and smothers the fire. Automatic sprinklers and deluge systems are also effective. 

Provide adequate fixed fire protection for tanks and vessels containing flammable, unstable or reactive materials. This can include fire loops with hydrants and monitors in the storage area, foam systems for individual tanks, and deluge spray systems to keep the exposed surfaces of tanks cool in case of fire in an adjacent tank. 

Provide fire suppression deluge protection in areas having high concentrations of flammables or combustibles Test reactive and critical raw materials prior to use Sample to confirm concentrations Label all containers... 

Provide safe separation distances Install fixed fire protection and alarms, water sprays (deluge), and/or foam systems activated by flammable gas, flame, and/or smoke detection devices... 

Provide automatic area sprinkler/deluge protection... 

For filter boxes, provide remote and automatic filter box lid closing on trip of appropriate fire detection device. Fire detection device may also be interlocked to stop solvent feed, trip deluge internal to filter box and/or trip inert gas blanket for filter box (caution, be aware inert gas is a potential asphyxiation hazard)... 

Critical Equipment Equipment, instrumentation, controls, or systems whose malfunction or failure would likely result in a catastrophic release of highly hazardous chemicals, or whose proper operation is required to mitigate the consequences of such release. (Examples are most safety systems, such as area LEL monitors, fire protection systems such as deluge or underground systems, and key operational equipment usually handling high pressures or large volumes.)... 

The use of appropriate instruments to monitor equipment operation and relevant process variables will detect, and provide warning of, undesirable excursions. Otherwise tliese can result in equipment failure or escape of chemicals, e.g. due to atmospheric venting, leakage or spillage. Instruments may facilitate automatic control, emergency action such as coolant or pressure relief or emergency shutdown, or the operation of water deluge systems. 

There are two philosophies regarding how to best slow a runaway reaction. One view holds that simple water deluge is the best method as it provides immediate cooling and dilution. The anti position is that the batch should be deluged and neutralized simultaneously. Kumpinsky reports that minimum self-heat rates occur between pH 4 and 7 [78]. Since neutralization involves production of additional heat, because the pH of a runaway batch is rarely known, and since the phenolic reactions are catalyzed by acid, base, and salt it seems likely that simple deluge is the surest method. 

The third line includes fixed fire protection systems (sprinklers, water sprays, or deluge systems, monitor guns, etc.), dikes, designed drainage systems, and other systems that control or iiiitigaic ha. ardous releases. 

Note PAGE 97 3 FAILURES IN 4253100 HOURS SIGNIFICANT LKG FIRE DELUGE VLV... 

Monitors and deluge sets-Many chemical plants use monitors for general use and for high hazard locations in order to provide maximum water supply with a minimum of manpower exposure. Deluge sets supported by ample hose streams are preferred for some protection uses. 

There is a deluge of papers, as well as of methods and of approaches, addressed to these problems. It is significant that in this blossoming of studies there is space for very simple models (as regards the material composition of the model) as well as for very complex models with a high degree of realism in the chemical composition. 

V. cholerae is a gram-negative bacillus. Vibrios pass through the stomach to colonize the upper small intestine. Vibrios have filamentous protein extensions that attach to receptors on the intestinal mucosa, and their motility assists with penetration of the mucus layer.2 The cholera enterotoxin consists of two subunits, one of which (subunit A) is transported into the cells and causes an increase in cyclic AMP, which leads to a deluge of fluid into the small intestine.20 This large volume of fluid results in the watery diarrhea that is characteristic of cholera. The stools are an electrolyte-rich isotonic fluid, the loss of which results in blood volume depletion followed by low blood pressure and shock.2 Of note, the diarrheal fluid is highly infectious. 

To protect against structural failure, water-deluge systems are usually installed to keep vessels and structural steelwork cool in a fire. 

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