Dehydrogenation kinetics

T.R. Jensen, A. Andreasen, T. Vegge, J.W. Andreasen, K. Stahl, A.S. Pedersen, M.M. Nielsen, A.M. Molenbroek, F. Besebbacher, Dehydrogenation kinetics of pure and nickel-doped magnesium hydride investigated by in situ time - resolved powder X-ray diffraction, Int. J. Hyd. Ener. 31 (2006) 2052-2062. 

A. Andreasen, Effect of Ti-doping on the dehydrogenation kinetic parameters of lithium aluminum hydride , J. Alloys Compd. 419 (2006) 40-44. 

A. Andreasen, T. Vegge, A.S. Pedersen, Dehydrogenation kinetics of as-received and ball-milled LiAlH , J. Solid State Chem. 178 (2005) 3672-3678. 

Dehydrogenation kinetics were measured in a differential reactor while... 

For all temperatures, the addition of transition metal compounds enhances the hydrogenation and dehydrogenation kinetics. Metal oxide, chloride or fluoride additions lead to a signiflcant enhancement ofthe reaction kinetics, especially during desorption [57]. 

Titanium has also been found to enhance the dehydrogenation kinetics of LiAlH4. Balema et found that LiAHTj could be transformed into Li3AlH6... 

Improved dehydrogenation kinetics and reduced thermodynamic stability are being sought through fundamental investigations of the crystalline structure, chemical binding status, particle size and morphology of the borohydrides, and also the distribution of the catalyst. 

Buyanov RA, Pakhomov NA (2001) Catalysts and processes for paraffin and olefin dehydrogenation. Kinet Catal 42 72-85... 

AG Zwahlen, JB Agnew. Isobutane dehydrogenation kinetics determination in a modified berty gradientless reactor. Ind Eng Chem Res 31 2088-2093, 1992. 

The derivation of Eq. (16) was based on the assumption that the energy of the bond between the hydrogen and the surface varies with the degree of coverage and that the dehydrogenation kinetics are determined by the maximum energy of the bond at sections which remain uncovered by adsorbed hydrogen. If there is... 

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