Radium decay scheme

The Uranium-Radium Series. This series commences with 318U and ends with the stable isotope n6Pb. The decay scheme is represented by ... 

Table 3-2 lists important physical properties of radium and selected radium compounds. Radioactive properties of the four naturally-occurring radium isotopes are listed in Table 3-3. In addition to the naturally occurring isotopes, there are 12 other known isotopes of radium. The principal decay schemes of the uranium and thorium decay series that produce the naturally-occurring radium isotopes are presented in Figure 3-1.

Evidence for the second viewpoint comes from measurements of longer-lived radionucleides within the radium decay sequence, specifically bismuth-210 and lead-210. The major routes for nuclei conversion within the radium decay scheme are shown in Fig. 7-27. The direct decay product of radium-226, an alpha-emitter, is radon-222, which escapes the Earth surface. Only the continents are a source the contribution from the oceans is negligible. Since the half-life time of radon-222 is only 3.8 days, its distribution in the troposphere is rather uneven. Over the continents the mixing ratio declines with increasing altitude (see Fig. 1-9). Over the oceans, the vertical gradient is reversed, as the oceans act as a sink and the zonal circulation keeps supplying material from the middle and upper troposphere. The immediate... 

Fig. 7-27. Major routes within the radium decay scheme. Half-life times are shown in years (y), days (d), or seconds (s).

In today s parlance, we call the radium emanation radon-222. (Like radium, the word radon comes from the Latin radius, for ray or beam. ) The alpha decay of radium-226 produces radon-222 and helium-4. The thorium emanation is radon-220, but the decay scheme from thorium-232 is more involved (see Problem 19.11). Rn-222 and Rn-220 are the two longest-lived isotopes of radon, the heaviest and rarest of the noble gases. (There are now 36 known isotopes of radon with mass numbers ranging from 193 to 228.) For many years, Dorn was generally credited as the sole discoverer of radon. However, as noted above, Ernest Rutherford and his co-workers, particularly Frederick Soddy, should be given at least equal billing. 

Even though some of the daughters in natural radioactive decay schemes have very short half-lives, all are present because they are constantly forming as well as decaying. It is likely that only about one gram of radium-226 was present in several tons of uraniiun ore processed by Marie Curie in her discovery of radium in 1898. Nevertheless, she was successful in isolating it. The ore also contained only a fraction of a milligram of polonium, which she was able to detect but not isolate. 

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