Decanal, reduction

N,N -linked synthesis, 5, 269 6,6 -Biazulenes synthesis, 1, All Bibenzimidazolyls 3-oxides synthesis, 5, 412 1,1 - Bibenzimidazolyls synthesis, 5, 459 2,2 -Bibenzo[b]selenienyl synthesis, 4, 947 2,2 -Bibenzothiazolyl reduction, 6, 260 4,4 -Bichromenyl synthesis, 3, 743 Bicyclo[n. 1.0]alkanes retro-cycloaddition reactions, 1, 668 Bicyclo[5.3.0]decane synthesis, 1, 420 Bicyclo[4.1,0]diheteroheptanes synthesis, 3, 977... 

Aluminum chloride, 45, 109 with lithium aluminum hydride, in reduction of l,4-dioxaspiro[4 5] decane 47, 37... 

Docosanedioic acid has been prepared by Wolff-Kishner reduction of 6,17-diketodocosanedioic acid, formed by reaction of the half-ester acid chloride of adipic acid with the a,co-cadmium derivative of decane (%26 overall yield).3 Reduction of Wolff-Kishner method, followed by simultaneous reduction and desulfurization with Raney nickel of the 2,5-bis(co-carboxyoctyl)thiophene pro-... 

Influence of sulfur dioxide on the selective catalytic reduction of NO by decane on Cu catalysts. 

Reasonable NO conversion can be achieved using n-decane as reductant. In the absence of sulfur dioxide, the catalytic activity is roughly related to the r ucibility of the Cu phase of Cu ions in zeolites the reaction temperature needed to reach 20% NO conversion parallels that of the TPR peak (Table 7). This relation also practically holds for Cu on simple oxides, therefore a redox mechanism in which reduction of Cu + cations is the slow step could account for the results. 

Brosius, R., Bazin, P., Thibault-Starzyk, F. et al., (2005) Operando FTIR study of reaction pathways of selective catalytic reduction of NOx with decane in the presence of water on iron-exchanged MFI-type zeolite, J. Catal., 234, 191. 

Delahay, G., Guzman-Vargas, A. and Coq, B. (2007) Deactivation of a Fe-ZSM-5 catalyst during the selective catalytic reduction of NO by n-decane An operando DRIFT study, Appl. Catal. B Environ., 70, 45. 

Lithium aluminum hydride, with aluminum chloride, for reduction of 4-f-butylcydohexanone, 47,17 in reduction of 1,4-dioxaspiro[4.5J-decane, 47, 38... 

The photocycloaddition of an excess of cyclobutenecarboxylic acid (380) and (—)-piperitone (381), followed by esterification with diazomethane, gave the adduct (382). Reduction of (382) afforded the lactone (383). Upon thermolysis in decane at 174 °C, the lactone (383) was converted to the dihydroisoaristolactone (384). Thermolysis of (382) in refluxing decane gave quantitative yield of the compound... 

REDUCTION OF ALKYL HALIDES AND TOSYLATES WITH SODIUM CYANOBOROHYDRIDE IN HEXAMETHYL-PHOSPHORAMIDE (HMPA) A. 1-IODODECANE TO n—DECANE B. 1-DODECYL TOSYLATE TO n-DODECANE, 53, 107 REDUCTION OF KETONES BY USE OF TOSYLHYDRAZONE DERIVATIVES ANDROSTAN-17 0—OL, 52, 122 REDUCTIVE AMINATION WITH SO-... 

The non-aqueous system of spherical micelles of poly(styrene)(PS)-poly-(isoprene)(PI) in decane has been investigated by Farago et al. and Kanaya et al. [298,299]. The data were interpreted in terms of corona brush fluctuations that are described by a differential equation formulated by de Gennes for the breathing mode of tethered polymer chains on a surface [300]. A fair description of S(Q,t) with a minimum number of parameters could be achieved. Kanaya et al. [299] extended the investigation to a concentrated (30%, PI volume fraction) PS-PI micelle system and found a significant slowing down of the relaxation. The latter is explained by a reduction of osmotic compressibihty in the corona due to chain overlap. 

Coq, B Tachon, D Figueras, F Mabilon, G Prigent, M. Selective catalytic reduction of nitrogen monoxide by decane on copper-exchanged mordenites. Appl. Catal, B Environmental, 1995, Volume 6, Issue 3, 271-289. 

Reduction of lactams to amines resembles closely the reduction of amides except that catalytic hydrogenation is much easier and was accomplished even under mild conditions. a-Norlupinone (l-azabicyclo[4.4.0]-2-oxodecane) was converted quantitatively to norlupinane (l-azabicyclo[4.4.0]decane) over platinum oxide in 1.25% aqueous hydrochloric acid at room temperature and atmospheric pressure after 16 hours [1122]. Reduction of the same compound by electrolysis in 50% sulfuric acid over lead cathode gave 70% yield [1122]. 

Redaction of / -toluenesulfonyIhydrazides by complex hydrides yidds hydrocarbons. The TV -tosyl hydrazide of stearic acid gave a 50-60% yield of octa-decane on reduction with lithium aluminum hydride [577]. 

Wiseman and coworkers have succeeded in preparing tricyclo[5.3.0.0 ]decane (393), a CioHig hydrocarbon which unlike adamantane is chiral. Their elegantly simple approach entails Diels-Alder addition of cyclobutene to l,4-dihalocyclohexa-l,3-dienes, catalytic hydrogenation of the adduct, reaction with aluminium triiodide, and ultimately di- -butyltin dihydride reduction. 

Ganter has developed three different approaches to tricyclo[5.2.1.0 ]decane (403), yet another of the nineteen isomeric hydrocarbons of adamantaneland As seen in Scheme XXXIII, the routes involve intramolecular cyclization of keto tosylate 399 followed by Wolff-Kishner reduction of the resulting ketone, thermo-cyclization of 400 and subsequent dechlorination, hydrogenation, and photocycli-zation of aldehydes 401. Majerski s approach involved hypoiodite cleavage of alcohol 402... 

REDUCTION OF CARBOXYLIC ACIDS TO ALDEHYDES 6-OXODECANAL (Decanal, 6-oxo-)... 

The trifluoroacetates of 1-hexanol and 1-heptanol had retention times of 3.0 and 5.1 minutes, respectively, on Carbowax at 80°C. The trifluoroacetates of 1-undecanol, nonane-1,9-diol, and decane-1,10-diol had retention times of 4.0, 5.1, and 7.6 minutes on Apiezon at 170°C. Peaks were well formed and did not have the characteristic tail of alcohol peaks. The reduction-trifluoroacetylation treatment of 5-ketohexanoic... 

In another approach 145, dibromocarbene was added to ( + )-cyclononadiene 127 to give (after reduction of the outside adduct) ( + )-trans-bicyclo[7.1.0]decane 132). From the dextrorotatory enantiomer of the above-mentioned dibromo-derivative 128, ( + )-trans-bicyclo[6,1.0]nonane 129) was accessible. Comparison of the chiroptical properties of (+)-129 and (+)-132 led to the conclusion that 127 had the (+)(/ )(axial) chirality145) in agreement with the results reported above 144). 

In the synthesis of the head-to-head [4 + 4] dimer of cyclopentadiene, the preferential reductive fission of the C3-C4 bond in bishomocubane again plays a significant role.43 Thus, catalytic hydrogenation of bishomocubane-6,10-diol (14) over 10% palladium on charcoal in ethyl acetate at 2.7-3.4 atmospheres for two days furnished the bishomosecocubanediol tetracy-clo[5.2.1.02,< .04 8]decane-5,10-diol (15).43... 

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