Cyclopentadienyl complex bisphosphine ruthenium

Recent efforts to explore the synthesis and reactivity of organotransition metal complexes with the cyclopentadienyl bisphosphine ruthenium auxiliary have emphasized the potential of this system for the development of new organic synthetic methods, but they have also uncovered a number of stumbling blocks which must be overcome to achieve real success in this area. Future developments in the chemistry of these ruthenium complexes will be based on the successful application of the reactivity trends uncovered in the past work. The rapid expansion of studies in this field since the mid-1980s has made it increasingly difficult for the synthetic chemist to... 

An interesting synthesis of the cyclopentadienyl bisphosphine ruthenium nitrosyl complex 9 involves the thermal displacement of both phenyl groups from (i75-C5H5)Ru(NC))PIi2 (8) with a chelating diphosphine [Eq. (6)] (72). Infrared data indicate that the nitrosyl ligand is linear (3 e ... 

T-acetylide ruthenium complexes with the [Ru (ri -C5R5)L2] fragment (C5R5 = cyclopentadienyl, indenyl L2 = mono- or bisphosphines) as the electron donor group. These complexes display in the visible intense MLCT absorptions, which dominate the (3 responses, and, compared with... 

---