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Anions cyclopentadienyl

The acidity of cyclopentadiene provides convincing evidence for the special sta bility of cyclopentadienyl anion... [Pg.458]

Write resonance structures for cyclopentadienyl anion suffi cient to show the delocalization of the negative charge over all five carbons J... [Pg.459]

C and melts at 173°C. It is iasoluble ia water but dissolves ia alcohols, ether, and benzene. Ferrocene can be prepared by numerous methods, including the reaction of cyclopentadienyl anion, with anhydrous FeCl2. Its extensive reaction chemistry is notable for the aromaticity of the... [Pg.441]

Pyrrole has a planar, pentagonal (C2 ) stmcture and is aromatic in that it has a sextet of electrons. It is isoelectronic with the cyclopentadienyl anion. The TT-electrons are delocalized throughout the ring system, thus pyrrole is best characterized as a resonance hybrid, with contributing stmctures (1 5). These stmctures explain its lack of basicity (which is less than that of pyridine), its unexpectedly high acidity, and its pronounced aromatic character. The resonance energy which has been estimated at about 100 kj/mol (23.9 kcal/mol) is intermediate between that of furan and thiophene, or about two-thirds that of benzene (5). [Pg.354]

Figure 11.15 shows the Fliickel MOs of cyclopentadienyl anion. Like benzene and cyclo-heptatrienyl cation, cyclopentadienyl anion has six tt electrons and a closed-shell electron configuration. [Pg.458]

Electrostatic potential map for cyclopentadienyl anion shows most negatively-charged regions (in red) and less negatively-charged regions (in blue). [Pg.183]

The CC bond distances in cyclopentadienyl anion, C5H5, are all equal, because the anion is aromatic (see Chapter 12, Problem 10). Electrophiles that interact electrostaticaUy with the anion, such as Na", interact equally with all five carbons, and do not disturb the anion s aromatic character. On the other hand, electrophiles that make covalent bonds, such as H", might interact more strongly with one particular carbon and destroy the aromaticity of the ring. [Pg.184]

Describe the similarities and differences in geometries, charge distributions and electrostatic potential maps for cyclopentadienyl sodium, cyclopentadiene and cyclopentadienyl anion. [Pg.184]

Problem 15.6 Draw the five resonance structures of the cyclopentadienyl anion. Are all carbon-carbon bonds equivalent How many absorption lines would you expect to see in the lH NMR and, 3C NMR spectra of the anion ... [Pg.527]

Figure 15.9 Pyrrole and imidazole are five-membered, nitrogen-containing heterocycles but have six tt electron arrangements, much like that of the cyclopentadienyl anion. Both have a lone pair of electrons on nitrogen in a p orbital perpendicular to the ring. Figure 15.9 Pyrrole and imidazole are five-membered, nitrogen-containing heterocycles but have six tt electron arrangements, much like that of the cyclopentadienyl anion. Both have a lone pair of electrons on nitrogen in a p orbital perpendicular to the ring.
N t/ l Five cyclopentadienyl molecular orbitals 4f Cyclopentadienyl cation (four 77 electrons) 4f Cyclopentadienyl radical (five 77 electrons) -H- Cyclopentadienyl anion (six 7r electrons)... [Pg.531]

Active Figure 15.11 Energy levels of the five cyclopentadienyl molecular orbitals. Only the six-7r-electron cyclopentadienyl anion has a filled-shell configuration leading to aromaticity. Sign in at www.thomsonedu.com to see a simulation based on this figure and to take a short quiz. [Pg.531]

Other kinds of substances besides benzene-like compounds can also be aromatic. For example, the cyclopentadienyl anion and the cycloheptatrienyl cation are aromatic ions. Pyridine, a six-membered, nitrogen-containing heterocycle, is aromatic and resembles benzene electronically. Pyrrole, a hve-membered heterocycle, resembles the cyclopentadienyl anion. [Pg.539]

Conjugated chains, 14, 46 Correlation diagrams, 44, 50 Cyclobutadiene, 171 Cyclobutane, 47, 222 orbital ordering, 26 through-space interactions, 26 Walsh orbitals, 27 Cyclobutene, 200 Cyclohexane, 278 Cyclohexene (half-boat), 274 Cyclopen tadiene, 225 Cvclopen tadienone, 269 Cyclopentadienyl anion, 237 Cyclopentane, 254 Cyclopen ten e, 241 Cyclopropane, 41, 47, 153 construction of orbitals, 19, 22 Walsh orbitals, 22, 36, 37 Cyclopropanone, 48, 197 bond lengths, 38 Cyclopropen e, 49, 132 reactivity, 40... [Pg.303]

Two commonly used synthetic methodologies for the synthesis of transition metal complexes with substituted cyclopentadienyl ligands are important. One is based on the functionalization at the ring periphery of Cp or Cp metal complexes and the other consists of the classical reaction of a suitable substituted cyclopentadienyl anion equivalent and a transition metal halide or carbonyl complex. However, a third strategy of creating a specifically substituted cyclopentadienyl ligand from smaller carbon units such as alkylidynes and alkynes within the coordination sphere is emerging and will probably find wider application [22]. [Pg.101]


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Analogues of the Cyclopentadienyl Anion

Antiaromatic compounds cyclopentadienyl anion

Aromatic rings cyclopentadienyl anion

Aromaticity cyclopentadienyl anion

Aromaticity, cycloheptatrienyl cation cyclopentadienyl anion and

Carbanions cyclopentadienyl anion

Cyclooctatetraenyl dianion cyclopentadienyl anion

Cyclopentadiene cyclopentadienyl anion from

Cyclopentadienyl anion Vilsmeier-Haack reaction

Cyclopentadienyl anion dinuclear complexes

Cyclopentadienyl anion electronic configuration

Cyclopentadienyl anion formation from cyclopentadiene

Cyclopentadienyl anion ligand structure

Cyclopentadienyl anion resonance structures

Cyclopentadienyl anion, aromaticity electrostatic potential map

Cyclopentadienyl anion, aromaticity molecular orbitals

Cyclopentadienyl anion, formation

Cyclopentadienyl complexes anionic

Cyclopentadienyl-anion, point group

Cyclopentadienyl-iron anions

Electrostatic potential map cyclopentadienyl anion

Frost circles cyclopentadienyl anion

Metal-Bonded Cyclopentadienyl Anions

Molecular orbitals cyclopentadienyl anion

Stability cyclopentadienyl anion

The Cyclopentadienyl Anion and Cation

Triphospholyl anions, formation ruthenium cyclopentadienyl complexes

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