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Correlation diagrams

J. Michl, in Photochemical Reactions Correlation Diagrams and Energy Barriers, G. Klopman, ed.. Chemical Reactivity and Reaction Paths, John Wiley Sons, Inc., New York, 1974. [Pg.398]

As an example, we shall discuss the Diels-Alder reaction of 2-methoxybuta-l,3-diene with acrylonitrile. Figure 3-7 gives the reaction equation, the correlation diagram of the HOMOs and LUMOs, and the orbital coefficients of the correlated HOMO and LUMO. [Pg.179]

Figure 3-7. FMO trealirent of a) a Dlels-Alder reaction equation, b) correlation diagram, c) orbital coefficients,... Figure 3-7. FMO trealirent of a) a Dlels-Alder reaction equation, b) correlation diagram, c) orbital coefficients,...
Seetion treats the spatial, angular momentum, and spin symmetries of the many-eleetron wavefunetions that are formed as anti symmetrized produets of atomie or moleeular orbitals. Proper eoupling of angular momenta (orbital and spin) is eovered here, and atomie and moleeular term symbols are treated. The need to inelude Configuration Interaetion to aehieve qualitatively eorreet deseriptions of eertain speeies eleetronie struetures is treated here. The role of the resultant Configuration Correlation Diagrams in the Woodward-Hoffmann theory of ehemieal reaetivity is also developed. [Pg.3]

Connecting the energy-ordered orbitals of reactants to those ofproducts according to symmetry elements that are preserved throughout the reaction produces an orbital correlation diagram. [Pg.187]

A. Plots of CSF Energies Give Configuration Correlation Diagrams... [Pg.290]

B. CSFs Interaet and Couple to Produee States and State Correlation Diagrams... [Pg.290]

Configuration correlation diagram for homonuclear case in which homolytic bond cleavage is energetically favored. [Pg.303]

State correlation diagram for heteronuclear case in which both heterolytic bond cleavage products are energetically favored relative to homolytic cleavage. [Pg.311]

Orbital-correlation diagram for the reaction C2H2 -h C-----> C3H2... [Pg.336]

Figure 1.1. Orbital correlation diagram illustrating the distinction between normal electron demand (leftside) and inverse electron demand (right side) Diels-Alder reactions. Figure 1.1. Orbital correlation diagram illustrating the distinction between normal electron demand (leftside) and inverse electron demand (right side) Diels-Alder reactions.
The seventh tool is the scatter or correlation diagram also known as an XY plot (50). This plot of one variable vs another is most useful in confirming interrelationships. Thus, scatter diagrams can verify the relationships shown in the cause and effect diagram. [Pg.371]

Q7 PROCESS CHART. PARETO ANALYSIS, CAUSE AND EFFECT DIAGRAM, HISTOGRAM, CORRELATION DIAGRAMS, PROCESS CONTROL CHARTS, CHECK SHEETS... [Pg.267]

A more complete analysis of interacting molecules would examine all of the involved MOs in a similar wty. A correlation diagram would be constructed to determine which reactant orbital is transformed into wfiich product orbital. Reactions which permit smooth transformation of the reactant orbitals to product orbitals without intervention of high-energy transition states or intermediates can be identified in this way. If no such transformation is possible, a much higher activation energy is likely since the absence of a smooth transformation implies that bonds must be broken before they can be reformed. This treatment is more complete than the frontier orbital treatment because it focuses attention not only on the reactants but also on the products. We will describe this method of analysis in more detail in Chapter 11. The qualitative approach that has been described here is a useful and simple wty to apply MO theory to reactivity problems, and we will employ it in subsequent chapters to problems in reactivity that are best described in MO terms. I... [Pg.53]

The cyclobutene-butadiene interconversion can serve as an example of the reasoning employed in construction of an orbital correlation diagram. For this reaction, the four n orbitals of butadiene are converted smoothly into the two n and two a orbitals of the ground state of cyclobutene. The analysis is done as shown in Fig. 11.3. The n orbitals of butadiene are ip2, 3, and ij/. For cyclobutene, the four orbitals are a, iz, a, and n. Each of the orbitals is classified with respect to the symmetiy elements that are maintained in the course of the transformation. The relevant symmetry features depend on the structure of the reacting system. The most common elements of symmetiy to be considered are planes of symmetiy and rotation axes. An orbital is classified as symmetric (5) if it is unchanged by reflection in a plane of symmetiy or by rotation about an axis of symmetiy. If the orbital changes sign (phase) at each lobe as a result of the symmetry operation, it is called antisymmetric (A). Proper MOs must be either symmetric or antisymmetric. If an orbital is not sufficiently symmetric to be either S or A, it must be adapted by eombination with other orbitals to meet this requirement. [Pg.609]

Fig. 11.4. Correlation diagram for cyclobutene and butadiene orbitals (symmetry-forbidden disrotatory reaction). Fig. 11.4. Correlation diagram for cyclobutene and butadiene orbitals (symmetry-forbidden disrotatory reaction).
Correlation diagrams can be constructed in an analogous fashion for the disrotatory and conrotatory modes for interconversion of hexatriene and cyclohexadiene. They lead to the prediction that the disrotatory mode is an allowed process whereas the conrotatory reaction is forbidden. This is in agreement with the experimental results on this reaction. Other electrocyclizations can be analyzed by the same method. Substituted derivatives of polyenes obey the orbital symmetry rules, even in cases in which the substitution pattern does not correspond in symmetiy to the orbital system. It is the symmetry of the participating orbitals, not of the molecule as a whole, that is crucial to the analysis. [Pg.611]

We have now considered three viewpoints from which thermal electrocyclic processes can be analyzed symmetry characteristics of the frontier orbitals, orbital correlation diagrams, and transition-state aromaticity. All arrive at the same conclusions about stereochemistiy of electrocyclic reactions. Reactions involving 4n + 2 electrons will be disrotatory and involve a Hiickel-type transition state, whereas those involving 4n electrons will be conrotatory and the orbital array will be of the Mobius type. These general principles serve to explain and correlate many specific experimental observations made both before and after the orbital symmetry mles were formulated. We will discuss a few representative examples in the following paragraphs. [Pg.614]

How do orbital symmetry requirements relate to [4tc - - 2tc] and other cycloaddition reactions Let us constmct a correlation diagram for the addition of butadiene and ethylene to give cyclohexene. For concerted addition to occur, the diene must adopt an s-cis conformation. Because the electrons that are involved are the n electrons in both the diene and dienophile, it is expected that the reaction must occur via a face-to-face rather than edge-to-edge orientation. When this orientation of the reacting complex and transition state is adopted, it can be seen that a plane of symmetry perpendicular to the planes of the... [Pg.638]

An orbital correlation diagram can be constructed by examining the symmetry of the reactant and product orbitals with respect to this plane. The orbitals are classified by symmetry with respect to this plane in Fig. 11.9. For the reactants ethylene and butadiene, the classifications are the same as for the consideration of electrocyclic reactions on p. 610. An additional feature must be taken into account in the case of cyclohexene. The cyclohexene orbitals tr, t72. < i> and are called symmetry-adapted orbitals. We might be inclined to think of the a and a orbitals as localized between specific pairs of carbon... [Pg.639]

Fig. 11.10. Orbital correlation diagram for ethylene, butadiene, and cyclohexene orbitals. Fig. 11.10. Orbital correlation diagram for ethylene, butadiene, and cyclohexene orbitals.
When the orbitals have been classified with respect to symmetry, they can be arranged according to energy and the correlation lines can be drawn as in Fig. 11.10. From the orbital correlation diagram, it can be concluded that the thermal concerted cycloadditon reaction between butadiene and ethylene is allowed. All bonding levels of the reactants correlate with product ground-state orbitals. Extension of orbital correlation analysis to cycloaddition reactions involving other numbers of n electrons leads to the conclusion that the suprafacial-suprafacial addition is allowed for systems with 4n + 2 n electrons but forbidden for systems with 4n 7t electrons. [Pg.640]

Show, by constructing a correlation diagram, whether each of the following disrotatory cyclizations is symmetiy allowed ... [Pg.651]

The complementary relationship between thermal and photochemical reactions can be illustrated by considering some of the same reaction types discussed in Chapter 11 and applying orbital symmetry considerations to the photochemical mode of reaction. The case of [2ti + 2ti] cycloaddition of two alkenes can serve as an example. This reaction was classified as a forbidden thermal reaction (Section 11.3) The correlation diagram for cycloaddition of two ethylene molecules (Fig. 13.2) shows that the ground-state molecules would lead to an excited state of cyclobutane and that the cycloaddition would therefore involve a prohibitive thermal activation energy. [Pg.747]


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