Current, electrical emitter

The bipolar junction transistor (BIT) consists of tliree layers doped n-p-n or p-n-p tliat constitute tire emitter, base and collector, respectively. This stmcture can be considered as two back-to-back p-n junctions. Under nonnal operation, tire emitter-base junction is forward biased to inject minority carriers into tire base region. For example, tire n type emitter injects electrons into a p type base. The electrons in tire base, now minority carriers, diffuse tlirough tire base layer. The base-collector junction is reverse biased and its electric field sweeps tire carriers diffusing tlirough tlie base into tlie collector. The BIT operates by transport of minority carriers, but botli electrons and holes contribute to tlie overall current. 

Electron Capture Detector In the electron capture detector (ECD), a beta emitter such as tritium or 63Ni is used to ionize the carrier gas. Electrons from the ionization migrate to the anode and produce a steady current. If the GC effluent contains a compound that can capture electrons, the current is reduced because the resulting negative ions move more slowly than electrons. Thus, the signal measured is the loss of electrical current. The ECD is very sensitive to materials that readily capture electrons. These materials frequently have unsaturation and electronegative substituents. Because the ECD is sensitive to water, the carrier gas must be dry. 

If there is one clear need in the field of OLED materials it continues to be in the area of blue emitters. A blue emissive material with good color coordinates CIE (0.10, <0.10) coupled with long device lifetime (>10,000 h) and high electrical efficiency (>5 cd/A) is the holy grail of materials chemists in this field. A major effort to find such materials continues in many laboratories including our own and the current sets of available materials may be supplanted at any time. However, the current best candidate blue emitters in the SMOLED area compromise many desirable properties — the most troublesome being long lifetime. 

In practice, moderate heating of the emitter at constant current serves to reduce adsorption to its surface during FI measurements. Heating at a constant rate (1-8 mA min ) is frequently employed to enforce desorption of analytes from the emitter in FD-MS. To avoid electric discharges resulting from too massive ion de-... 

A calorimetric method may be used where an electric heater is imbedded in the object of interest, and the power dissipated by the element is accurately calculated from voltage and current. Once steady state is established and the object is at constant temperature, the body must emit radiation at the same rate at which it is supplied. As long as conduction and convection are eliminated as mechanisms of heat transfer (e.g. vacuum conditions), the blackbody temperature is known by Rt = o"T4. The emittance can then be determined after py-rometric measurements of the brightness temperature of the object. 

In the above studies [41, 490, 491, 519], the emitter has been heated by passing an electric current through it. The source and sample inlet temperatures were not necessarily the same as that of the emitter. It has been shown that under these circumstances the sample molecules may not accommodate fully to the emitter temperature prior to ionization [122]. The broad significance of this suggestion is that the studies [41, 490, 491, 519] would have underestimated the effects of temperature upon rates of decompositions. 

Further flue gas desulfurization development eflForts are currently directed toward solving this constraint through the ultimate production of elemental sulfur. It should be noted, however, that even recovery of 40% of the total sulfur emitted from industrial and electric utility emitters... 

Reisse and co-workers [147-149] were the first to describe a novel device for the production of metal powders using pulsed sonoelectrochemical reduction. This device exposes only the flat circular area at the end of the sonic tip to the electrodeposition solution. The exposed area acts as both cathode and ultrasound emitter, named by Reisse et al. as sonoelectrode . A pulse of electric current produces a high density of fine metal nuclei. This is immediately followed by a burst of ultrasonic energy that removes the metal particles from the cathode, cleans the surface of the cathode, and replenishes the double layer with metal cations by stirring the solution. In [145], a list is given of chemically pure fine crystalline powders, mostly metals or metallic alloys, prepared by this method, with particle sizes varying between 10 and 1000 run depending on deposition conditions. 

---