Cumenyl hydroperoxide

SYNS CUMEENHYDROPEROXYDE pUTCH) CUMENE HYDROPEROXIDE pOT) CUMENE HYDROPEROXIDE, TECHNICALLY PURE pop CUMENT HYDROPEROXIDE CUMENYL HYDROPEROXIDE CUMOLHYDROPEROXID (GERMAN) CUMYL HYDROPEROXIDE O-CUMYL mT)ROPEROXIDE CUMYL HYDROPEROXIDE, TECHNICAL PURE pop o,a-DIMETHYLBENZYL HYDROPEROXIDE (MAK) HYDROPEROXYDE de CUMENE (FRENCH) HYDROPEROXYDE de CUMYLE (FRENCH) IDROPEROSSIDO di CUMENE (ITALIAN)... 

Beilstein Handbook Reference) BRN 1908117 CCRIS 3801 CHP Cumeenhydroperoxyde Cumene hydroperoxide Cumenyl hydroperoxide Curnolhydroperoxid Cumolhydroperoxide Cumyl hydroperoxide EINECS 201-254-7 HSDB 254 Hydroperoxide, a,a-dimethylbenzyl Hydroperoxide de cumene ... 

Synonyms CHP Cumenyl hydroperoxide Cumyl hydroperoxide a-Cumyl hydroperoxide a,a-Dimethylbenzyl hydroperoxide 7-Hydroperoxyku-men Isopropylbenzene hydroperoxide Classification Organic peroxide Empirical CsHiiO ... 

Cumenyl hydroperoxide Cumyl hydroperoxide oc-Cumyl hydroperoxide. See Cumene hydroperoxide Cumyl peroxide. See Dicumyl peroxide... 

A diselenide, 2,2 -diseleno-bis-P-cyclodextrin accepts a variety of hydroperoxides as substrates (Liu et al. 2000). The glutathione peroxidase-like activities, reduction of H2O2, ferf-butyl hydroperoxide and cumenyl hydroperoxide by glutathione were 7.4,4.5 and 10.2 U/ unol, respectively. In contrast to ebselen, the diselenide displayed high glutathione peroxidase-like activity. The reduction of hydroperoxide by glutathione in the presence of a radical trap showed that the mimic catalyses the reaction via a non-radical mechanism. 

Diazopropane passed at 0°/400mm into a soln. of cumenyl hydroperoxide in abs. cyclohexane or petroleum ether, and if necessary allowed to stand until the color has disappeared cumenyl propyl peroxide. Y 65.1%. F. e. and limitations s. H. Kropf, C.-R. Bernert, and L. Dahlenburg, Tetrahedron 26, 3279 (1970). 

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