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Crystals, diffraction of X-rays

Many scientifically and teclmologically important substances caimot be prepared as single-crystals large enough to be studied by single crystal diffraction of x-rays and, especially, neutrons. If a sample composed of... [Pg.1381]

The equation nA = 2d sin 9 is known as the Bragg equation. The important result of this equation is that at any particular angle of incidence 9, only X-rays of a particular wavelength fulfill the requirement of staying in phase and being reinforced, and are therefore diffracted by the crystal. Diffraction of X-rays by crystals forms the basis of XRD for crystal structure determination and is also the reason XRF spectrometry is possible, as will be seen. [Pg.547]

A scattering process will also result in polarization of x-rays according to the classical Thompson theory expressed by Eq. (2.1). For an unpolarized primary beam, scattering at an angle (26) of 90° results in nearly complete plane polarization of the scattered x-rays. Thus, crystal diffraction of x-rays produces plane-polarized radiation. If the diffraction angle (26) approaches 90°, polarization becomes nearly complete. [Pg.37]

Bragg W L 1913 The structure of some crystals as indicated by their diffraction of X-rays Proo. R Soo. A 89 248-60... [Pg.1383]

Because of Bragg s explanation of diffraction of x-rays from a crystal as being like reflections from famihes of planes, the diffraction spots ate usually called "reflections." Each reflection is identified with three integer indices, h, k, and / For the set of planes shown in Figure 7, the indices of the corresponding reflection are /i = 1, = 0, and I = 2. [Pg.375]

Figure 18.6 Diffraction of x-rays by a crystal, (a) When a beam of x-rays (red) shines on a crystal all atoms (green) in the crystal scatter x-rays in all directions. Most of these scattered x-rays cancel out, but in certain directions (blue arrow) they reinforce each other and add up to a diffracted beam, (b) Different sets of parallel planes can be arranged through the crystal so that each corner of all unit cells is on one of the planes of the set. The diagram shows in two dimensions three simple sets of parallel lines red, blue, and green. A similar effect is seen when driving past a plantation of regularly spaced trees. One sees the trees arranged in different sets of parallel rows. Figure 18.6 Diffraction of x-rays by a crystal, (a) When a beam of x-rays (red) shines on a crystal all atoms (green) in the crystal scatter x-rays in all directions. Most of these scattered x-rays cancel out, but in certain directions (blue arrow) they reinforce each other and add up to a diffracted beam, (b) Different sets of parallel planes can be arranged through the crystal so that each corner of all unit cells is on one of the planes of the set. The diagram shows in two dimensions three simple sets of parallel lines red, blue, and green. A similar effect is seen when driving past a plantation of regularly spaced trees. One sees the trees arranged in different sets of parallel rows.
Wavelength Spectrometry (WDS) is based upon the phenomenon of Bragg diffraction of X rays incident on a crystal. The difiraction phenomenon is described by the expression ... [Pg.180]

The classical approach for determining the structures of crystalline materials is through diflfiaction methods, i.e.. X-ray, neutron-beam, and electron-beam techniques. Difiiaction data can be analyzed to yield the spatial arrangement of all the atoms in the crystal lattice. EXAFS provides a different approach to the analysis of atomic structure, based not on the diffraction of X rays by an array of atoms but rather upon the absorption of X rays by individual atoms in such an array. Herein lie the capabilities and limitations of EXAFS. [Pg.222]

Bijvoet, J.M., Burgers, W.G. and Hagg, G. (1972) Early Papers on Diffraction of X-rays by Crystals (Int. Union of Crystallography, Utrecht) pp. 5. [Pg.147]

M. von Laue (Frankfurt) discovery of the diffraction of X-rays by crystals. [Pg.1300]

Bragg equation An equation relating the angle of diffraction of x-rays to the spacing of layers of atoms in a crystal (X = 2d sin 6). [Pg.943]

X-ray diffraction occurs in the elastic scattering of X-ray photons by atoms in a periodic lattice. The scattered monochromatic X-rays that are in phase give constructive interference. Figure 4.4 illustrates how diffraction of X-rays by crystal planes allows one to derive lattice spacings by using the Bragg relation ... [Pg.131]

Figure 2.68 The diffraction of X-rays from a crystal lattice. Figure 2.68 The diffraction of X-rays from a crystal lattice.
Structure determination has greatly advanced with the invention of new ways to use x-ray crystallography, mainly new mathematical methods that permit the interpretation of the observed patterns of diffraction of x-rays by a crystal, translating it into the molecular structures in the crystal. A Nobel Prize in 1985 to Herbert Hauptmann and Jerome Karle recognized such an advance. [Pg.62]

The diffraction of x-rays by crystalline substances is of great analytical interest, since it is only by pure coincidence that two compounds would form crystals in... [Pg.14]

The mathematics necessary to understand the diffraction of X rays by a crystal will not be discussed in any detail here. Chapter 4 of reference 10 contains an excellent discussion. The arrangement of unit cells in a crystal in a periodic manner leads to the Laue diffraction conditions shown in equations 3.3 where vectors a, b, and c as well as lattice indices h, k, and l have been defined in Figure 3.5 and S is a vector quantity equal to the difference between the resultant vector s after diffraction and the incident X-ray beam wave vector So so that S = s - So-... [Pg.78]

Unlike the case of diffraction of light by a ruled grating, the diffraction of x-rays by a crystalline solid leads to the observation that constructive interference (i.e., reflection) occurs only at the critical Bragg angles. When reflection does occur, it is stated that the plane in question is reflecting in the nth order, or that one observes nth order diffraction for that particular crystal plane. Therefore, one will observe an x-ray scattering response for every plane defined by a unique Miller index of (h k l). [Pg.191]

It is of interest to attempt to cast the absorption-edge spectrum in a form resembling a diffraction function. In conventional diffraction of X-rays or electrons by gases, liquids, or crystals, the general diffraction function expresses the ratio of scattered intensity, 7 to incident intensity, 7o, as a function of (sin 0)/, where d is half the scattering angle ... [Pg.152]

It is common for liquid nitrogen frozen protein crystals to acquire a patina of ice on the surface of the cryoprotectant. Diffraction of X-rays from even small ice crystals can mask reflections from the protein crystal. In addition, the presence of excessive amounts of ice can obscure the true position of the nylon loop, thereby resulting in the failure to place the crystal in the X-ray beam. It is, therefore, essential to remove ice crystals prior to diffraction analysis. [Pg.179]

Fluorapatite (FA) corresponds to the chemical formula Caio(P04)eF2 and crystallises in the hexagonal space group PGs/m, with Z = 1 and unit-cell parameters a = b = 9.367 A and c = 6.884 A [1] (Fig. 2). From a structural viewpoint, fluorapatite is often considered as a crystalline model for other apatites and is seen as a reference apatitic array [2]. It is one of the very first apatite structures to have been solved. It has been thoroughly studied since the 1930s [3] and is well documented in the literature. In particular, Sudarsanan et al. [1] reported the single crystal refinement of X-ray diffraction (XRD) data, and the detailed description of atomic positions and local symmetry is fully available [4,5],... [Pg.284]

Diffraction of X-rays by a crystal. Diffraction by a three-dimensional-array of atoms might be expected to present a complex geo ... [Pg.120]

Modem structural chemistry differs from classical structural chemistry with respect to the detailed picture of molecules and crystals that it presents. By various physical methods, including the study of the structure of crystals by the diffraction of x-rays and of gas molecules by the diffraction of electron waves, the measurement of electric and magnetic dipole moments, the interpretation of band spectra, Raman spectra, microwave spectra, and nuclear magnetic resonance spectra, and the determination of entropy values, a great amount of information has been obtained about the atomic configurations of molecules and crystals and even their electronic structures a discussion of valence and the chemical bond now must take into account this information as well as the facts of chemistry. [Pg.4]

A great amount of information about the structure of crystals has been obtained by use of the x-ray diffraction method. The diffraction of x-rays by crystals was discovered by Max von Laue in 1912. Shortly thereafter W. L. Bragg discovered the Bragg equation, and in 1913 he and his father, W. H. Bragg, published the first structure determinations of crystals. [Pg.70]


See other pages where Crystals, diffraction of X-rays is mentioned: [Pg.517]    [Pg.517]    [Pg.1364]    [Pg.1367]    [Pg.1379]    [Pg.240]    [Pg.67]    [Pg.21]    [Pg.344]    [Pg.679]    [Pg.149]    [Pg.205]    [Pg.462]    [Pg.198]    [Pg.173]    [Pg.4]    [Pg.5]    [Pg.139]    [Pg.517]    [Pg.52]    [Pg.1760]    [Pg.1249]    [Pg.1026]   
See also in sourсe #XX -- [ Pg.309 , Pg.312 ]




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