Crystallographic spacing values

The crystallographic spacing values and their assigned Miller indicies are listed below in Table II. 

Table 4.1 Geometric properties of some periodic minimal surfaces. The "genus" of each three-periodic minimal surface (IPMS) is the genus of a unit cell of the IPMS (with symmetrically distinct sides). The "symmetry" refers to the crystallographic space group for the surface (assuming equivalent sidesl.liie surfaces are tabulated in order of deviation of the homogeneity index from the "ideal" value of 3/4. ...

Table 17.1 Crystallographic data of the hexagonal and cubic closest-packings of spheres. +F means +(j,0), +(j,0, j), +(0, j, j) (face centering). Values given as 0 or fractional numbers are fixed by space-group symmetry (special positions)...

Crystallographic data have not been published for calcium leucovorin, but literature values do exist for the barium salt.7 Diffraction patterns could not be obtained on all samples although they had been recrystallized several times. Interplanar spacings are listed, but these numbers appear to change with the amount of moisture present in the sample. 

In the solid-state photoreaction of 24c, a more chemoselective reaction occurred and only p-thiolactam 25c was obtained almost quantitatively. Of particular importance is the finding that the solid-state photoreaction of 24c involves a crystal-to-crystal nature where the optically active p-thiolactam 25c is formed in specific yield. Furthermore, the X-ray crystallographic analysis revealed that the crystals of 24c are chiral, and the space group is P2j. Irradiation of crystals at 0 °C exclusively gave optically active P-thiolactam 25c, in 81% yield at 100% conversion (entry 5). As expected, the thiolactam 25c showed optical activity (81% ee). This reaction exhibited good enantioselectivity throughout the whole reaction, where a small difference was observed in the ee value from 97 to 81% ee with increasing conversion from 20 to 100% (entries 5 and 6). The solid-state photoreaction also proceeded without phase separation even after 100% reaction conversion. The crystal-to-crystal nature of the transformation was confirmed by X-ray diffraction spectroscopy. 

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