Crystallizers in series

Curve 4 exhibits very steep solubility. Yield is obtained by cooling the feed solution. To prevent fines formation, the cooling must exactly follow the solubility curve. This is done automatically in batch crystallizers. Continuous crystallizers in series must have the crystallizer stage temperatures selected so as not to cross the solubility curve. Benzoic acid and DMT exhibit this type of solubility. 

In order to increase the driving force for crystallization or increase the yield per pass through the system, a continuous crystallization system can be intentionally operated as a cascade, as shown in Fig. 7-9. A significant number of these crystallizers in series become, in effect, a plug flow reactor. 

Grier, D.G. (editor) (1998) A series of papers on colloidal crystals, in MRS Bulletin, October 1998. 

In these cases, the product is reslurried with pure liquor or fresh solvent if the solubility is not too high, and refiltered. In order to meet the required product impurity level, several such washings may take place in series. See Coulson and Richardson (1991) and Mullin (2001) for design guides and examples calculations. It is noted that impurities retained within liquid occlusions are particularly difficult to remove without first crushing the crystals. 

Budz, J., Jones, A.G. and Mullin, J.W., 1987b. Agglomeration of potassium sulphate in an MSMPR crystallizer. In Fundamental aspects of crystallization and precipitation processes, American Institute of Chemical Engineers. Symposium Series, No. 253, 83, New York American Institute of Chemical Engineers, pp. 78-84. 

Heffels, S.K., de Jong, E.J. and Nienoord, M., 1994. Improved operation and control of batch crystallizers. In Particle design via crystallization, American Institute of Chemical Engineers Symposium Series, 87(284), 170-181. 

Witkowski, W.R., Miller, S.M. and Rawlings, J.B., 1990. Light scattering measurements to estimate kinetic parameters of crystallization. In Crystallization as a separation process, ACS Symposium Series, 438, 102. 

The molecular structure and dynamics of the ice/water interface are of interest, for example, in understanding phenomena like frost heaving, freezing (and the inhibition of freezing) in biological systems, and the growth mechanisms of ice crystals. In a series of simulations, Haymet and coworkers (see Refs. 193-196) studied the density variation, the orientational order and the layer-dependence of the mobilitity of water molecules. The ice/water basal interface is found to be a relatively broad interface of about... 

According to this model, the SEI is made of ordered or disordered crystals that are thermodynamically stable with respect to lithium. The grain boundaries (parallel to the current lines) of these crystals make a significant contribution to the conduction of ions in the SEI [1, 2], It was suggested that the equivalent circuit for the SEI consists of three parallel RC circuits in series combination (Fig. 12). Later, Thevenin and Muller [29] suggested several modifications to the SEI model ... 

Polymeric Liquid Crystals in Materials Science and Technology Series , edited by A. Cifferi, W. R. Krigbaum, R, B, Meyer, Academic Press, N. Y. 1982... 

A series of calculations on defect centers induced by radiation damage in alpha-quartz is reported. Ab initio SCF-MO calculations were carried out on a 21 atom cluster, Si50i6 % surrounded by 956 point-ions, designed to simulate alpha-quartz. This two-region approach made it possible to represent the long-range electrostatic effects, present in the crystal, in the SCF-MO cluster. 

In the multistage process described on Fig. 20-14 feed enters one of several crystallizers installed in series. Crystals formed in each crystallizer are transferred to a hotter stage and the liquid collected in the clarified zone of the crystallizer is transferred to a colder stage and eventually discharged as residue. At the hot end, crystals are transferred to a vertical purifier where countercurrent washing is performed by pure, hot-product reflux. TSK refers to this multistage process as the countercurrent cooling crystallization (CCCC) process. In... 

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