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Crystallinity transport

The epitaxy reactor is a specialized variant of the tubular reactor in which gas-phase precursors are produced and transported to a heated surface where thin crystalline films and gaseous by-products are produced by further reaction on the surface. Similar to this chemical vapor deposition (CVE)) are physical vapor depositions (PVE)) and molecular beam generated deposits. Reactor details are critical to assuring uniform, impurity-free deposits and numerous designs have evolved (Fig. 22) (89). [Pg.523]

During the conversion process, the object is to create uranium hexafluoride (UF ), a highly corro-sh e substance that is gaseous at high temperatures, but is a white crystalline solid at lower temperatures. Uranium hexafluoride is easily transported in its ciystalline form to an enrichment facility (the step taken after conversion), but the gaseous form is well suited for the enrichment process, itself. First, the... [Pg.868]

Radiochemical studies indicate that the pore base is the actual site of formation of aluminium oxide, presumably by transport of aluminium ions across the barrier-layer, although transport of oxygen ions in the opposite direction has been postulated by some authorities. The downward extension of the pore takes place by chemical solution, which may be enhanced by the heating effect of the current and the greater solution rate of the freshly formed oxide, but will also be limited by diffusion. It has been shown that the freshly formed oxide, y -AljOj, is amorphous and becomes slowly converted into a more nearly crystalline modifipation of y-AljO . [Pg.692]

After the fiber-like lithium has grown, lithium is still deposited on the lithium substrate that is not at the tip of the fiber-like lithium. If the deposition continues for a long time, the lithium electrode becomes covered with long, fiber-like lithium. In this situation, lithium-ion transport in the electrolyte to the lithium electrode surface is hindered by the fiber-like lithium. Then, lithium begins to be deposited on the tip and on kinks of the fiber-like lithium, where there are crystalline defects. The morphology of the deposited lithium is particle-like or amorphous. As there are many kinks, the current density of the lithium deposition becomes very low. This low current density may create particle-like, rather than fiber-like, lithium. Thus the morphology of the lithium as a whole becomes mushroom-like [31]. [Pg.345]

Scale and corrosion debris transport results in FW line/feed pump blockages Impingement and erosion Poor deaerator venting Sticking check valves Fe, Cu, Ni, Zn, Cr oxides Crystalline magnetite... [Pg.302]

Alloys are metallic materials prepared by mixing two or more molten metals. They are used for many purposes, such as construction, and are central to the transportation and electronics industries. Some common alloys are listed in Table 5.5. In homogeneous alloys, atoms of the different elements are distributed uniformly. Examples include brass, bronze, and the coinage alloys. Heterogeneous alloys, such as tin-lead solder and the mercury amalgam sometimes used to fill teeth, consist of a mixture of crystalline phases with different compositions. [Pg.324]


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