Critical angle of total reflection

For very thin sample thickness t and a scattering angle 29 that is well above the critical angle of total reflection, the exponential factor is approximately unity and a simple background subtraction without consideration of absorption is allowed. Symmetrical-reflection geometry is only a special case of asymmetrical-reflection geometry. 

The underlying idea behind these measurements is to irradiate the single ciystal we wish to stndy at a very low angle, below the critical angle of total reflection. As... 

The polymer properties in thin films are then compared with the bulk as measured by FTIR attenuated total reflection spectroscopy (ATR). A modest refractive index of the internal reflection element (IRE made of ZnSe, n=2.43 at 2000 cm ) and an incident angle of 65° - still low but well above the critical angle of total reflection - are chosen for the p-polarized light in order to obtain an information depth of several microns. Hence, the ATR spectra provide the bulk properties of the polymer sample. 

ReflEXAFS EXAFS at a grazing angle below the critical angle of total reflection... 

In Abbe s double prism method a thin ho-meotropically oriented nematic film is placed between the hypotenuse faces of two rectangular prisms. Using light polarized parallel and perpendicular to the optical axis, respectively, the principal refractive indices and can be obtained directly from the critical angle of total reflection, provided that the refractive index of the prism is greater than that of the liquid crystal [2, 8-10]. In some cases the director of the nematic phase was oriented uniformly parallel to the prism planes [11-14]. Special variants of the total reflection method have been described [3, 4, 15, 16]. A total reflection refractometer of the Abbe type has also been used to determine n, n and An in the infrared region between 2.5 and 14 p.m [17]. 

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