Creep Ductile-brittle transition

However, at lower constant loads the rate of crystal plastic deformation decreases and (at 80 °C) disentanglement becomes competitive leading to the development of isolated planar craze-like defects extending perpendicular to the tensile axis (Fig. 15). The ensuing concentration of stress will further localize most of the sample deformation in such creep crazes and lead to a macroscopic ductile-brittle transition—in this material observed at 20 MPa (Fig. 14 [67]). 

Liao, T.W., Flexural strength of creep feed ground ceramics general pattern, ductile-brittle transition and MLP modeling. International Journal cf Machining Tools Manufacturing, 1998, 38(4), 257-275. 

Hardness and a ductile-to-brittle transition temperature (DBTT) have also been noted to follow a Hall-Petch relationship (Meyers, and Chalwa, 1984). Ductility increases as the grain size decreases. Decreasing grain size tends to improve fatigue resistance but increases creep rate. Electrical resistivity increases as grain size decreases, as the mean free path for electron motion decreases. 

Rhenium (Re) differs from the other refractory metals (Nb, Ta, Mo and W) in that it has an hep structure, and does not form carbides. Because it does not have a ductile-to-brittle transition temperature. Re retains its ductility from subzero to high temperatures. In addition, it can be mechanically formed and shaped to some degree at room temperature. It also has a very high modulus of elasticity that, among metals, is second only to those of Ir and Os. Compared with other refractory metals. Re has superior tensile strength and creep-rupture strength over a wide temperature range. 

The following topics are addressed in this chapter simple fracture (both ductile and brittle modes), fundamentals of fracture mechanics, fracture toughness testing, the ductile-to-brittle transition, fatigue, and creep. These discussions include failure mechanisms, testing techniques, and methods by which failure may be prevented or controlled. 

Pal] reported mechanical properties (compressive yield strength (0.2%) and creep) and oxidation behavior of Fe-(10-43.5) at.% Al-(10-33) at.% Ti alloys in the temperature range of 20 to 1100°C. The microstracture of these alloys after heat treatment at 800, 900 and 1000°C were either single phase (L2i or C14) or two-phase (L2i -1- C14 or B2 + 72 (Mn23The)). The ductile to brittle transition temperature (DBTT) falls between 675 and 900°C. Oxidation behavior of some alloys at 900C exhibits parabolic behavior. 

Pal] Mechanical tests Hardness, compressive yield stress, ductile-to-brittle transition temperature, steady state creep rate, and oxidation kinetics... 

Creep leads ultimately to rupture, referred to as creep-rupture, stress-rupture or static fatigue. Creep-rupture of thermoplastics can take three different forms brittle failure at low temperatures and high strain rates ductile failure at intermediate loads and temperatures and slow, low energy brittle failure at long lifetimes. It is this transition back to brittle failure that is critical in the prediction of lifetime, and it is always prudent to assume that such a transition will occur [1], A notch or stress concentration will help to initiate failure. 

The first secondary transition below Tg, the so called fj-relaxation, is practically important. This became evident after Struik s (1978) finding that polymers are brittle below Tp and establish creep and ductile fracture between Tp and Tg. The p-relaxation is characteristic for each individual polymer, since it is connected with the start of free movements of special short sections of the polymer chain. In view of more recent data of Tp Boyer s relation, Eq. (6.29), is very approximate and fails completely for amorphous polymers with high Tg s (e.g. aromatic polycarbonates and polysulphones). Some rules of thumb may be given for a closer approximation. 

Single-crystal and poly crystalline transition metal carbides have been investigated with respect to creep, microhardness, plasticity, and shp systems. The fee carbides show slip upon mechanical load within the (111)plane in the 110 direction. The ductile-to-brittle transformation temperature of TiC is about 800 °C and is dependent on the grain size. The yield stress of TiC obeys a Hall Petch type relation, that is, the yield stress is inversely proportional to the square root of the grain size. TiC and ZrC show plastic deformation at surprisingly low temperatures around 1000 °C. 

Several cautions are, however, in order. Polymers are notorious for their time dependent behavior. Slow but persistent relaxation processes can result in glass transition type behavior (under stress) at temperatures well below the commonly quoted dilatometric or DTA glass transition temperature. Under such a condition the polymer is ductile, not brittle. Thus, the question of a brittle-ductile transition arises, a subject which this writer has discussed on occasion. It is then necessary to compare the propensity of a sample to fail by brittle crack propagation versus its tendency to fail (in service) by excessive creep. The use of linear elastic fracture mechanics addresses the first failure mode and not the second. If the brittle-ductile transition is kinetic in origin then at some stress a time always exists at which large strains will develop, provided that brittle failure does not intervene. 

Since the transition metal elements in these ternary Laves phases can substitute for each other freely, and since the distribution of Laves phase can be controlled by thermomechanical treatments there are possibilities for optimizing such NiAl alloys with Laves phases with respect to creep resistance and the brittle-to-ductile transition temperature (BDTT) by controlling the composition and phase distribution, and this is being studied presently... 

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