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Diamines, couplings

Halogenation of pyrimidine bases may be done with bromine or iodine. Bromination occurs at the C-5 of cytosine, yielding a reactive derivative, which can be used to couple diamine spacer molecules by nucleophilic substitution (Figure 1.48) (Traincard et al., 1983 Sakamoto et al., 1987 Keller et al., 1988). Other pyrimidine derivatives also are reactive to bromine compounds... [Pg.56]

Basic, forms a stable water-soluble dihydrochloride. Diazotization gives brown azodyes (Bismarck brown) owing to the coupling of the partially diazotized base with the excess of diamine. Is also used as an end component of many azo-dyes, readily coupling with one or two molecules of diazo compound. [Pg.305]

The most noteworthy reaction of azo-compounds is their behaviour on reduction. Prolonged reduction first saturates the azo group, giving the hydrazo derivative (C NH-NH C), and then breaks the NH NH linkage, with the formation of two primary amine molecules. If method (1) has been employed to prepare the azo-compound, these two primary amines will therefore be respectively (a) the original amine from which the diazonium salt was prepared, and (6) the amino derivative of the amine or phenol with which the diazonium salt was coupled. For example, amino-azobenzene on complete reduction gives one equivalent of aniline, and one of p-phenylene diamine, NHaCeH NH benzene-azo-2-naphthoI similarly gives one equivalent of aniline and one of... [Pg.210]

Primary aromatic diamines cannot be diazotised (tetrazotised) and coupled normally. Thus o-])henylenediamiiie yields a triazole derivative and m-phenylenediamine gives an azo dye (Bismarck brown) by selfcoupling. [Pg.648]

The next method Strike has for semi-direct amination is really weird, Strike is really exposing Strike s ignorance of chemistry with this dog. But if one looks hard at the articles cited, the potential is there. The authors came up with this little procedure that produced vicinal diamines out of alkenes [83]. Later they found that if they did a couple of things different, they would end up with a monoamine with the majority product being at the beta carbon. The following is a conjoining of the two paper s experimentals ... [Pg.186]

Oxidation H ir Colorant. Color-forming reactions are accompHshed by primary intermediates, secondary intermediates, and oxidants. Primary intermediates include the so-called para dyes, -phenylenediamine, -toluenediamine, -aminodiphenylamine, and p- am in oph en o1, which form a quinone monoimine or diimine upon oxidation. The secondary intermediates, also known as couplers or modifiers, couple with the quinone imines to produce dyes. Secondary intermediates include y -diamines, y -aminophenols, polyhydroxyphenols, and naphthols. Some of the more important oxidation dye colors are given in Figure 1. An extensive listing is available (24,28). [Pg.456]

Pigment Red 144 [5280-784] 20735 disa2o condensation coupling of dia2oti2ed 2,5-dichloroaniline with 3-hydroxy-2-napthoic acid, foUowed by acid chloride formation and reaction with 2-chloro-/)-phen5iene- diamine... [Pg.20]

Other noncychc reactions are observed, especially in polyamides of longer carbon chain monomers for example, the linear analogue to the cychc amine reaction is diamine coupling (eq. 10) to form secondary amines that can act as branch points (eq. 11). [Pg.227]

Dyes. Sodium nitrite is a convenient source of nitrous acid in the nitrosation and diatozation of aromatic amines. When primary aromatic amines react with nitrous acid, the intermediate diamine salts are produced which, on coupling to amines, phenols, naphthols, and other compounds, form the important azo dyes (qv). The color center of the dye or pigment is the -N=N- group and attached groups modify the color. Many dyes and pigments (qv) have been manufactured with shades of the entire color spectmm. [Pg.200]

The polyimide shown is a tme thermosetting resin, but the general reaction procedure, coupling the dianhydride with the diamine, is extremely important throughout polyimide chemistry. The intermediate polyamic acid polymers form the basis for many of the polyimide resins used in advanced composites. [Pg.39]

Toluene diisocyanate Midget impinger 15 ml Marcali solution 1 25 95 Diazotlzation and coupling reaction Materials containing reactive hydrogen attached to oxygen (phenol) certain other diamines... [Pg.184]

This is not the only method of forming tetrazo-compounds. Each amino-group of a diamine may be diazotised and coupled. Benzidine and its homologues, which ha e been utilised in this way, have a special value for the cotton dyer, as the shades produced are not only ery biilliant, but, unlike the maiorily of... [Pg.290]

Oxidative coupling of o-nitrotoluene gives 4,4 -dinitrodibenzyl which is reduced with hydrogen to the diamine. The diamine is pyrolyzed to give dihydrobenzazepine. This is reacted with N-(3-chloropropvl)-N-methylbenzamine to give N-benzyldesipramine. This is debenzylated by reductive cleavage and then reacted with HCI. [Pg.443]

If an aromatic o-diamine such as 1,2-diaminobenzene (2.24) is diazotized in dilute aqueous acid, the 2-aminobenzene-l-diazonium ion formed first (2.25) undergoes a rapid intramolecular N-azo coupling reaction to give 1,2,3-benzotri-azole (2.26). Both amino groups of 2.24 can, however, be diazotized in concentrated acid (Scheme 2-18), forming the bis-diazonium ion 2.27. 1,3- and 1,4-diamines must also be bisdiazotized in concentrated acids in order to avoid inter-molecular N- or C-coupling. [Pg.24]

Aromatic block copolymers, 282-284 Aromatic copolyesters, 18 Aromatic coupling, catalysts for, 289 Aromatic diamines, 180... [Pg.577]

A few aromatic amines do not react e.g. -substituted diamines yield benzotriazoles that cannot couple [1]. [Pg.205]

The couphng of N-substituted benzaldimines, mediated by the zinc-copper couple in the presence of (+)-camphorsulfonic acid (CSA) in DMF, was investigated. The best results were obtained for the imine 22, and the optimal balance of yield, diastereoselectivity and enantioselectivity for the diamine 23 was obtained using 3equiv of (+)-CSA [17] (Schemes). How-... [Pg.7]


See other pages where Diamines, couplings is mentioned: [Pg.122]    [Pg.123]    [Pg.977]    [Pg.128]    [Pg.128]    [Pg.667]    [Pg.289]    [Pg.108]    [Pg.108]    [Pg.647]    [Pg.23]    [Pg.137]    [Pg.463]    [Pg.122]    [Pg.123]    [Pg.977]    [Pg.128]    [Pg.128]    [Pg.667]    [Pg.289]    [Pg.108]    [Pg.108]    [Pg.647]    [Pg.23]    [Pg.137]    [Pg.463]    [Pg.343]    [Pg.40]    [Pg.26]    [Pg.29]    [Pg.239]    [Pg.119]    [Pg.480]    [Pg.3]    [Pg.4]    [Pg.5]    [Pg.6]    [Pg.7]    [Pg.8]    [Pg.9]    [Pg.11]   
See also in sourсe #XX -- [ Pg.65 ]

See also in sourсe #XX -- [ Pg.65 ]




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1,2-Diamines coupling reactions

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