Coupling wavelength

In SPR sensors with angular modulation, the sensor output is the coupling wavelength kt and therefore the instrumental contribution to sensor sensitivity Srii is equal to Skr/Suef. By differentiating the coupling conditions for the prism, grating, and waveguide coupler (see Chap. 1 of this volume [1]) in ef and k, we obtain ... 

Fig. 2 SPR sensors based on modulation of a coupling angle, b coupling wavelength, and c light intensity...

Further optimization of this approach allowed the sensor to resolve changes in the coupling wavelength as low as 1.5 x 10 nm, which for the sensor sensitivity of 7500 nm RIU translates to a refractive index resolution Of2xl0- R1U [6]. 

The correlation fiinction G(/) quantifies the density fluctuations in a fluid. Characteristically, density fluctuations scatter light (or any radiation, like neutrons, with which they can couple). Then, if a radiation of wavelength X is incident on the fluid, the intensity of radiation scattered through an angle 0 is proportional to the structure factor... 

The chemical effects of ultrasound do not arise from a direct interaction with molecular species. Ultrasound spans the frequencies of roughly 15 kH2 to 1 GH2. With sound velocities in Hquids typically about 1500 m/s, acoustic wavelengths range from roughly 10 to lO " cm. These are not molecular dimensions. Consequently, no direct coupling of the acoustic field with chemical species on a molecular level can account for sonochemistry or sonoluminescence. 

Hg Cd Te is an example of a ternary detector, in which the value of x controls the cutoff wavelength. Photoconductive detectors are generally simpler to couple to low noise amplifiers photodiodes generally have lower power consumption because these have no external bias, and better high frequency performance (15,16). 

Pigure 10 shows the typical commercial performance of LEDs used for optical data communication. Both free-space emission and fiber-coupled devices are shown, the latter exhibiting speeds of <10 ns. Typically there exists a tradeoff between speed and power in these devices, however performance has been plotted as a function of wavelength for purposes of clarity. In communication systems, photodetectors (qv) are employed as receivers rather than the human eye, making radiometric power emitted by the devices, or coupled into an optical fiber, an important figure of merit. 

Thus far we have discussed the direct mechanism of dissipation, when the reaction coordinate is coupled directly to the continuous spectrum of the bath degrees of freedom. For chemical reactions this situation is rather rare, since low-frequency acoustic phonon modes have much larger wavelengths than the size of the reaction complex, and so they cannot cause a considerable relative displacement of the reactants. The direct mechanism may play an essential role in long-distance electron transfer in dielectric media, when the reorganization energy is created by displacement of equilibrium positions of low-frequency polarization phonons. Another cause of friction may be anharmonicity of solids which leads to multiphonon processes. In particular, the Raman processes may provide small energy losses. 

In Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES), a gaseous, solid (as fine particles), or liquid (as an aerosol) sample is directed into the center of a gaseous plasma. The sample is vaporized, atomized, and partially ionized in the plasma. Atoms and ions are excited and emit light at characteristic wavelengths in the ultraviolet or visible region of the spectrum. The emission line intensities are proportional to the concentration of each element in the sample. A grating spectrometer is used for either simultaneous or sequential multielement analysis. The concentration of each element is determined from measured intensities via calibration with standards. 

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