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Heisenberg Correspondence Principle

On the basis of Bohr s correspondence principle, Heisenberg postulated that a comparable set of quantum-mechanical canonical relations must exist, and... [Pg.86]

A classical mechanical % provides insights into intramolecular dynamics, guided by the powerful diagnostic tools of nonlinear classical dynamics. The action-angle representation of a classical mechanical problem is easily derived from the spectroscopic Heff. In fact, the action-angle picture lies at the core of Heisenberg s version of the Correspondence Principle (Heisenberg, 1925). The prescription is that... [Pg.717]

I — we will call it 5 — to the individual electron. The correct number of terms is obtained when we let Z = 0,1,2,... (For S-, P-, D. .. terms) and allow parallel positioning in the composition of the vectors. If classical mechanics is applied to this model and the action variables are fixed by quantum conditions, one obtains results that are valid only within the correspondence principle. The precise results are given by the new quantum mechanics of Heisenberg, Born and Jordan. In what follows we will distinguish between a model and an atom or molecule. To the model we apply cleissical pictures and quantum conditions (for instance we do not worry about an angular momentum of zero). The properties of a model and an atom or molecule transform into each other for large values of the quantum numbers. [Pg.200]

The Heisenberg uncertainty principle offers a rigorous treatment of the qualitative picture sketched above. If several measurements of andfi are made for a system in a particular quantum state, then quantitative uncertainties are provided by standard deviations in tlie corresponding measurements. Denoting these as and a, respectively, it can be shown that... [Pg.16]

This general expression relates the uncertainties in the simultaneous measurements of A and B to the commutator of the corresponding operators A and B and is a general statement of the Heisenberg uncertainty principle. [Pg.101]

The residual energy (designated of a harmonic oscillator in the ground state. The Heisenberg Uncertainty Principle does not permit any state of completely defined position and momentum. A one-dimensional harmonic oscillator has energy levels corresponding to ... [Pg.714]

Due to Heisenberg s uncertainty and Pauli s exclusion principles, the properties of a multifermionic system correspond to fermions being grouped into shells and subshells. The shell structure of the one-particle energy spectrum generates so-called shell effects, at different hierarchical levels (nuclei, atoms, molecules, condensed matter) [1-3]. [Pg.53]

The Heisenberg principle tells us that the energy uncertainty of a given state is inversely proportional to the uncertainty in the time during which the corresponding energy level is occupied ... [Pg.38]

J s are the operators corresponding to spin around the z-axis. In other words, we can measure the z-spin states of the two particles simultaneously. In contrast, it is impossible to measure both the x- and z-spins of a single particle simultaneously nor is it possible to measure both the position and the momentum of a dynamical particle simultaneously, by Heisenberg s uncertainty principle. The independence of our two measurements is crucial. [Pg.341]

When an atom emits radiation, the frequency of the corresponding photon is linked to the energy of the levels between which the transition occurs. According to the Heisenberg principle, if the excited state has a lifetime of A/, then this results in a minimum uncertainty for the energy AE, such that AEAt > h/lit. [Pg.284]

The measured half-life of the state is 89.4 ps, which corresponds to a energy width, T, or AE, due to the Heisenberg uncertainty principle of ... [Pg.242]

In quantum mechanics, Heisenberg s uncertainty principle states that there is a limit to which we can know the product of the uncertainties in a coordinate and its corresponding momentum, AxApx. Thus, even in quantum mechanics, there is a minimum volume in phase space in which we can localize a particle. [Pg.162]

The importance of Heisenberg s equation and of the corresponding hyper-vinal theorem for a stationary state in the description of the proMrties of the total system is maintained in the description of a subsystem. Indeed, the generalized action principle that is employed to establish the quantum... [Pg.146]


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See also in sourсe #XX -- [ Pg.716 ]




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Correspondence principle

Heisenberg principle

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