Copper-Catalyzed Arylations of Amines and Alcohols with Boron-Based Arylating Reagents

Copper-Catalyzed Arylations of Amines and Alcohols with Boron-Based Arylating Reagents 

Modem Aryhtion Methods. Edited by Lutz Ackermann 

Copyright 2009 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim 

This chapter will attempt to summarize selected key learnings and trends, and will also highlight recent developments of these methods solely devoted to the copper-catalyzed oxidative arylations of O—H and N—H bonds with boron-based arylating reagents. Further, it will detail some specifics that have brought the method to its current high levels of popularity within the synthetic organic chemistry community. 

Discovery and Development of a New O—H Bond Arylation Reaction From Stoichiometric to Catalytic in Copper 

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I 4 Copper-Catalyzed Arylations of Amines and Alcohols with Boron-Based Arylating Reagents Table 4.1 Stoichiometric and the first catalytic O—H bond arylation. 

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