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Continuous state function

Electroless reactions must be autocatalytic. Some metals are autocatalytic, such as iron, in electroless nickel. The initial deposition site on other surfaces serves as a catalyst, usually palladium on noncatalytic metals or a palladium—tin mixture on dielectrics, which is a good hydrogenation catalyst (20,21). The catalyst is quickly covered by a monolayer of electroless metal film which as a fresh, continuously renewed clean metal surface continues to function as a dehydrogenation catalyst. Silver is a borderline material, being so weakly catalytic that only very thin films form unless the surface is repeatedly cataly2ed newly developed baths are truly autocatalytic (22). In contrast, electroless copper is relatively easy to maintain in an active state commercial film thicknesses vary from <0.25 to 35 p.m or more. [Pg.107]

There is nothing in Equations 1-8 which is an all-or-none situation. There are no positive feedback loops which might cause some kind of flip-flop of states of operation of the system. There are some possibilities for saturation phenomena but all relationships are graded. Overall, transient or steady-state, the changes of concentration of P-myosin are continuous, monotonic functions of the intracellular Ca ion concentration. On this basis it is more appropriate to say that smooth muscle contraction is modulated rather than triggered by Ca ion. [Pg.179]

Initially we consider a simple atom with one valence electron of energy and wave function which adsorbs on a solid in which the electrons occupy a set of continuous states Tj, with energies Ej. When the adsorbate approaches the surface we need to describe the complete system by a Hamiltonian H, including both systems and their interaction. The latter comes into play through matrix elements of the form Vai = / We assume that the solutions T j to this eigen value problem... [Pg.236]

Continuous Transfer functions in polynomial or pole-zero form state-space models transport delay... [Pg.240]

The density of states is the central function in statistical thermodynamics, and provides the key link between the microscopic states of a system and its macroscopic, observable properties. In systems with continuous degrees of freedom, the correct treatment of this function is not as straightforward as in lattice systems - we, therefore, present a brief discussion of its subtleties later. The section closes with a short description of the microcanonical MC simulation method, which demonstrates the properties of continuum density of states functions. [Pg.15]

What is a delta (A) but an excuse for teachers to be lazy I call this the curse of delta. Too often delta is allowed to take on a life of its own without the student understanding that it symbolizes a change in some property between two different thermodynamic states. In fact as I write this piece 1 noted a colleague who referred to AG as a state function. The state function is G all right but delta just describes a process. How can a struggling student understand this crucial difference when as instructors we either, do not understand the difference ourselves, or continue to be imprecise in our use of language Instead of delta... [Pg.16]

The nuclei of the atoms in a solid and the inner electrons form ion cores with energy levels little different from corresponding levels in free atoms. The characteristics of the valence electrons arc modified greatly, however. The stale functions of these outer electrons greatly overlap those of neighboring atoms. Restrictions of the Pauli Exclusion Principle and the Uncertainty Principle force modification of the state functions, and the development of a set of split energy levels becomes a quasi-continuous band of levels of width, which are several electron volts for most solids. Importantly, unoccupied levels of the atoms are also split into bands. The electronic characteristics of solids are determined by the relative position in energy of the occupied and unoccupied levels as well as by die characteristics of the electrons within a band. [Pg.1518]

It thus seems that there is no direct link between volumetric and elastic properties in the glassy state and that the anomalous density variations cannot be attributed to a crosslink density effect, either direct (on molecular packing) or indirect (through internal antiplasticization as discussed below). It seems reasonable to correlate this behavior with the presence of unreacted epoxides. The density would be (in the systems under consideration) a continuously increasing function of the amine/epoxide ratio, owing to the... [Pg.300]

Figure 2.5 Integration contour for the analytically continued Nevanlinna function, f[z), displaying the new cut and deformations around bound states and resonance poles. Figure 2.5 Integration contour for the analytically continued Nevanlinna function, f[z), displaying the new cut and deformations around bound states and resonance poles.
Let = pf,c,p = grade, Fs, (3f,d = grad 0f,Us, T = grad Us be the array of fields describing the elastic state of our isothermal process and, in addition, let us enclose the relative velocity u and the solid one vH by imposing the principle of equipresence, we postulate that constitutive quantities Th, Ki, Ct, Si, m, M and a are all twice continuously differentiable functions with respect to all constitutive fields and require the consistency with the in-... [Pg.188]

If the states span a continuous, rather than a discrete, energy range, we can introduce a continuous distribution function, f (e) dr., the fraction of molecules that have energy in a range dr around e ... [Pg.140]

Thus, in potential sweep work, when the electrode potential is changed too quickly, the various intermediate radicals of the reaction will not correspond to the 0 s of the steady-state functioning of the reaction and the information obtained, and hence the mechanism determined from it may be irrelevant in providing the information needed for, say, the design of electrocatalysts to last for 3-6 months of continuous production with the reaction in the steady state.4 Thus, there is not much point in carrying out an academic mechanism investigation (mostly done with fast sweeps) because the time domains may be too short for radical buildup to the steady state. [Pg.90]

Consider a setup where the two-I-frame states are sent in a collision trajectory remember the I-frame is a classical physics device. The initial state is a direct product of state functions for each I-frame system at a collision point, they continue to be a simple product and they separate away as a simple product. This product defines a nonentangled state. [Pg.79]

The state of a system is described by a single-valued, continuous and bounded function T (wavefunction, or state function) of coordinates and time. [Pg.124]

According to the first postulate, the state of a physical system is completely described by a state function fifiq, /) or ket T1), which depends on spatial coordinates q and the time t. This function is sometimes also called a state vector or a wave function. The coordinate vector q has components q, q2, , so that the state function may also be written as q, q2, , t). For a particle or system that moves in only one dimension (say along the x-axis), the vector q has only one component and the state vector XV is a function of x and t Tfix, /). For a particle or system in three dimensions, the components of q are x, y, z and I1 is a function of the position vector r and t Tfi r, /). The state function is single-valued, a continuous function of each of its variables, and square or quadratically integrable. [Pg.86]


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See also in sourсe #XX -- [ Pg.194 ]




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Continuous function

Function continuity

Functional continuous

Functional state

Functions state function

State functions

State, continuity

System, continued state function

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