Constitutive relations momentum flux

The generic equations of balance are statements of truth, which is a priori self-evident and which must apply to all continuum materials regardless of their individual characteristics. Constitutive relations relate diffusive flux vectors to concentration gradients through phenomenological parameters called transport coefficients. They describe the detailed response characteristics of specific materials. There are seven generic principles (1) conservation of mass, (2) balance of linear momentum, (3) balance of ro-... 

The setting up of the constitutive relation for a binary system is a relatively easy task because, as pointed out earlier, there is only one independent diffusion flux, only one independent composition gradient (driving force) and, therefore, only one independent constant of proportionality (diffusion coefficient). The situation gets quite a bit more complicated when we turn our attention to systems containing more than two components. The simplest multicomponent mixture is one containing three components, a ternary mixture. In a three component mixture the molecules of species 1 collide, not only with the molecules of species 2, but also with the molecules of species 3. The result is that species 1 transfers momentum to species 2 in 1-2 collisions and to species 3 in 1-3 collisions as well. We already know how much momentum is transferred in the 1-2 collisions and all we have to do to complete the force-momentum balance is to add on a term for the transfer of momentum in the 1-3 collisions. Thus,... 

Chapter 1 serves to remind readers of the basic continuity relations for mass, momentum, and energy. Mass transfer fluxes and reference velocity frames are discussed here. Chapter 2 introduces the Maxwell-Stefan relations and, in many ways, is the cornerstone of the theoretical developments in this book. Chapter 2 includes (in Section 2.4) an introductory treatment of diffusion in electrolyte systems. The reader is referred to a dedicated text (e.g., Newman, 1991) for further reading. Chapter 3 introduces the familiar Fick s law for binary mixtures and generalizes it for multicomponent systems. The short section on transformations between fluxes in Section 1.2.1 is needed only to accompany the material in Section 3.2.2. Chapter 2 (The Maxwell-Stefan relations) and Chapter 3 (Fick s laws) can be presented in reverse order if this suits the tastes of the instructor. The material on irreversible thermodynamics in Section 2.3 could be omitted from a short introductory course or postponed until it is required for the treatment of diffusion in electrolyte systems (Section 2.4) and for the development of constitutive relations for simultaneous heat and mass transfer (Section 11.2). The section on irreversible thermodynamics in Chapter 3 should be studied in conjunction with the application of multicomponent diffusion theory in Section 5.6. 

A statement of the constitutive relation analogous to those for mass, heat, and momentum is that the flux due to migration in an electric field is proportional to the force acting on the particle multiplied by the particle concentration. The molar flux in stationary coordinates is then... 

In the limit of vanishingly small Reynolds numbers, forces due to convective momentum flux are negligible relative to viscous, pressure, and gravity forces. Equation (12-4) is simplified considerably by neglecting the left-hand side in the creeping flow regime. For fluids with constant /r and p, the dimensionless constitutive relation between viscons stress and symmetric linear combinations of velocity gradients is... 

The most common types of models in chemical engineering are those related to the transport of mass, heat, and momentum. In addition to the balance equation, a constitutive equation that relates the flux of interest to the dependent variable (e.g. mass flux to concentration) is needed. These relations (in simple ID form) for the microscopic level and for flow at the porous media level are given in Table 3.1. It should be noted that all these relations have the general form... 

The mass transfer flux law is analogous to the laws for heat and momentum transport. The constitutive equation for Ja, the diffusional flux of A resulting from a concentration difference, is related to the concentration gradient by Pick s first law ... 

A trivial solution to eqns (7.9) and (7.10) is simply the steady-state condition, e = eo (a constant) and Up = 0, which reduces the momentum equation, eqn (7.10), to = 0. Given a constitutive expression for F, this relation delivers the constant, steady-state solution eo for void fraction throughout the bed, a function solely of the fluid flux C/q. Such a solution represents the condition of homogeneous fluidization, and always satisfies the above particle-phase equations. The question now to be posed concerns the stability of this steady-state condition is it sustainable in the face of small fluctuations in void fraction or particle velocity Such... 

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