Complex ammines chlorates

These substances have a variable composition depending upon the reaction conditions, chiefly the concentration of the reagents used. Salvadori [119] called attention to the interesting explosive properties of the chlorates and perchlorates of complex ammines of the type ... 

Copper (II) ammine Explosive Complexes. Following complexes are listed in Vol 1 of this Encyclopedia Copper (II) ammine Azides, p A280 (See also Ref, p 149) Copper (ll) ammine Bro-mates p A281(See also Ref, p 387) Copper (II) ammine Chlorates, p A281(See also Ref, p 334) Copper (II) ammine lodates, p A281 (See also Ref, p 428 Copper (II) ammine Nitrates, pp A280 (See also item listed below) Copper (ll) ammine Perchlorates, p A28l(See also Ref, p 340)... 

Copper (II) ammine Nitrates. Several complexes of general formula, Cu(N03)2-xNH3- yHzO, are listed in Ref 2, pp 179-82. Izzo (Ref 1, p 214) lists the following blue signal light compn contg one of the complexes K chlorate 53, "nitrato di rame ammonicale 26, charcoal 16 sulfur 5%... 

Cupric Explosive Salts. See under AMMINE, Tables D E, Vol 1, p A280-81 Cupric Azide Complexes, Vol 1, p A533-L under Cupric Chlorate, Vol 2, p C188-L under List of Copper Compounds in this Volume and others, p C 515-R... 

It is remarkable for its ability to take part in the formation of coordination cqmpds, such.as ammines (See Vol 1 of Encycl, pp A275fO some of these compds are expl, as, for example, copper complexes described here under Ethylenediamine Complexes . On neutralization with nitric acid it forms the expl Ethylenediamine Dinitrate (See below), while under other conditions it gives the expl Echylenedinitramine, which, however, is usually prepd by nitrating ethyleneurea. Other expl compds, such as Di chlorate. Diperchlorate are prepd from ethylenediamine... 

JCS 124, 11, 767 (1923) CA 18, 362 (1924) iPrepn and some props of several cobalt ammines, such as hexammine-cobalt (ni) chlorite [Co(NH,),] (CIO ), HjO and chloropentamminecobalt (III) chlorite [Co(NH,)5 Cl] (ClOj)a are given. These complexes are less stable then the corresponding chlorates and perchlorates (See items Co20 and Co24 in table D) 11)W. Friederich P.Vervoorst, SS21, 4S>-52,... 

Thallium(Il) complexes, 171 Thallium(III) complexes, 171 amines, 172 ammines, 172 aqua, 172 bipyridyl, 172 bromates, 173 bromides, 174 carboxylates, 173 chlorates, 173 chlorides, 174 cyanides, 171 dichlorophosphates, 173 ethers, 173... 

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