Cupric chlorate

CUPRIC CHLORATE CUPRIC CHLORIDE CUPRIC NITRATE CUPRIC OXALATE CUPRIC SULFATE... 

A basic copper chlorate is formed when soln. of potassium chlorate acidified with sulphuric acid are electrolyzed with an alternating current between copper electrodes (L. Rossi) 83 when the hydrate is heated above 100° (A. Wachter) when a soln. of copper chlorate be mixed with pieces of marble or urea, and heated in a sealed tube to 130° (L. Bourgeois) when the hydroxides of the alkalies or alkaline earths act on cupric chlorate soln., or copper hydroxide acts on soln. of potassium chlorate (A. Brochet) when hydrated cupric oxide or cupric hydroxide acts on cupric chlorate soln. (P. Sabatier) or when potassium chlorate acts on cupric acetate soln. (A. Casselmann), basic cupric chlorate is obtained. The basic chlorate forms bluish-green monoclinic prisms of sp. gr. 3 55 and composition 4Cu0.C1205.3H20, that is, Cu(C103)2.3Cu(0H)2, which A. Werner considers to be hexahydroxyl cupric chlorate ... 

Amines, Complexes. A number of amine complexes with cupric chlorates, perchlorates and bromates were examined before WWII in France flnjj described mr... 

Copper (II) Chlorate. See Cupric Chlorate under Chlorates in Vol 2, p C188 and also Gmelin,... 

Cupric Explosive Salts. See under AMMINE, Tables D E, Vol 1, p A280-81 Cupric Azide Complexes, Vol 1, p A533-L under Cupric Chlorate, Vol 2, p C188-L under List of Copper Compounds in this Volume and others, p C 515-R... 

Cupric chlorate, Cu(C108)2.—The chlorate is prepared by dissolving cupric hydroxide or carbonate in chloric acid, or by the interaction of cupric sulphate and barium chlorate. On evaporation of the solution it separates in the form of the tetrahydrate, which melts and decomposes at 73° C.13... 

Heated with cupric chlorate, a black color. 

Anilin may be recognized by the following reactions (1.) With a nitrate and HaSO<, a red color. (3.) Cold HaSOi does not color it alone on addition of potassium dichromate, a fine blue color is produced, which, on dilution with water, passes to violet and, if not diluted, to black. (8.) With calcium hypochlorite, a violet color. (4J Heated with cupric chlorate, a black color. (5.) Heated with mercuric chlorid, a deep crimson color. (0.) In very... 

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