Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Commutative integration

We will conditionally refer to this situation as the case of commutative integrability of a Hamiltonian system and will examine it in more detail. [Pg.32]

As shown below, we have an important analogue of these assertions if the function / is replaced by the symplectic manifold momentum mapping induced hy a complete set of commuting integrals. In particular, one may examine one integral on a three-dimensional constant-energy surface of an integrable system. [Pg.70]

Theorem 2.2.2 (Fomenko). Let M be a smooth symplectic manifold and let a system v = sgrad H be integrated by smooth independent commuting integrals H = /i,/21 ,/n Let be any Sxed compact nonsingular common level... [Pg.111]

H(x) = h)i = 1 is compact, then the Hamiltonian system sgrad IT is completely Liouville-integrable by means of a complete set of commuting integrals which poly-nomially depend on /i,..., /m ... [Pg.177]

Consequently, Eqs. (43) and (59) are identical, for applications in a 3D parameter space, except that the vector product in the former is expressed as a commutator in the latter. Both are computed as diagonal elements of combinations of strictly off-diagonal operators and both give gauge independent results. Equally, however, both are subject to the limitations with respect to the choice of surface for the final integration that are discussed in the sentence following Eq. (43). [Pg.17]

The order in which these integrals are written is important, as the ilf-matrices for different t do not in general commute. [Pg.416]

Again we have dropped the mode index j momentarily. Note that the two exponentials cannot be combined since they do not commute. To evaluate the integral it is convenient to reintroduce the complete set of final states [cf. Eq. (19.22)] ... [Pg.269]

The expected value on the left-hand side is taken with respect to the entire ensemble of random fields. However, as shown for the velocity derivative starting from (2.82) on p. 45, only two-point information is required to estimate a derivative.14 The first equality then follows from the fact that the expected value and derivative operators commute. In the two integrals after the second equality, only /u,[Pg.264]

As a result, the exact CC equations are quartic equations for the tjm, tjjm n, etc. amplitudes. Although it is a rather formidable task to evaluate all of the commutator matrix elements appearing in the above CC equations, it can be and has been done (the references given above to Purvis and Bartlett are especially relevant in this context). The result is to express each such matrix element, via the Slater-Condon rules, in terms of one- and two-electron integrals over the spin-orbitals used in determining d including those in itself and the virtual orbitals not in . [Pg.373]

The presence of the minus sign in the argument of b in Eq. (5) gives the convolution integral the highly useful property of commutativity, that is,... [Pg.6]

In the Lamb shift, the Coulomb potential between proton and electron contributes to the commutator in the hydrogen atom, and the commutator with the free Hamiltonian becomes (h2e2/2)V2(l/r), which gives a delta function that is evaluated in the matrix element when written out by completeness as an integral over space ... [Pg.151]

Acquire and verify a certified calibrator (CRM) from which a working calibrator is to be prepared. A working calibrator should be verified for integrity, validated for commutability, and have documented metrological traceability. [Pg.223]

It can be shown from the commutation relations that a function cannot be an eigenfunction of more than one component of M, but can be an eigenfunction of M2 and one component of M simultaneously. To find expectation values from these wave functions, we need to define an operation of integration. We shall let the symbol (9A m > Mx9Am) represent such an operation. For electron-orbital motion where s a function of xyz, this operation becomes... [Pg.187]

In the second place, the Hamiltonian operators which occur and commute with all Or belong to the totally symmetric irreducible representation T1 (see Appendix A. 10-3) and integrals over them dT vanish unless T = T (see eqn (8-4.5)). Thus, in carrying out an approximate solution of the electronic Schrodinger equation, changing to a set of basis functions which belong to the irreducible representations will allow us, by inspection, to put many of the integrals which occur equal to zero. There will also, because of this, be an... [Pg.197]

It was shown in Section 1.7 that when the operators Px, PY, Pz °t>ey general angular-momentum commutation relations, as in (5.41), then the eigenvalues of P2 and Pz are J(J+ )h2 and Mh, respectively, where M ranges from — J to J, and J is integral or half-integral. However, we exclude the half-integral values of the rotational quantum number, since these occur only when spin is involved. [Pg.109]

When the integral in brackets in (7.6) vanishes, the electronic transition is forbidden. For example, since and )//, are both eigenfunctions of the Hermitian operator 5 (provided spin-orbit interaction is small), and since S2 commutes with del, we conclude [Equation (1.51)1 that electronic transitions with a change in S are forbidden (just as in atoms) ... [Pg.154]

A) commutes with 7 (A) and with Tx(X) (Problem 8.10), so that the transition-moment integral vanishes unless the states k and / have the same eigenvalue "(A) [Eq. (1.51)]. Thus the coupling constants JAA, which occur in "(A), do not appear in the expression for the transition frequencies. The same argument shows the transition frequencies to be independent of JX X/ Q.E.D. [Pg.183]

We can show (Problem 8.11) that // (A) commutes with each of the five terms of H and therefore commutes with H. Hence the eigenfunctions of H are also eigenfunctions of // (A) with eigenvalues "(A). For an applied rf field in the x direction, the transition probability between states k and / is proportional to the square of the following integral involving the... [Pg.432]

Exercise. For the present example the integral in (4.7b) turns out to be very simple. First prove the commutator identity [IB, W ] = a IB and then derive from it B (t) = eaf B. The result is... [Pg.394]

All rings will be commutative with 1. Once and for all we fix an algebraically closed field k All schemes will be assumed to be defined over k and noetherian and all sheaves will be quasi-coherent. By an algebraic scheme we mean a scheme of finite type over k. An integral scheme is one which is reduced and irreducible, if X and Y are schemes we will write X Y instead of XxkY < ). A variety is a reduced algebraic scheme a curve. resp. a surface, is a variety of pure dimension 1, resp. 2. [Pg.7]


See other pages where Commutative integration is mentioned: [Pg.34]    [Pg.149]    [Pg.166]    [Pg.171]    [Pg.192]    [Pg.193]    [Pg.34]    [Pg.149]    [Pg.166]    [Pg.171]    [Pg.192]    [Pg.193]    [Pg.430]    [Pg.297]    [Pg.517]    [Pg.87]    [Pg.204]    [Pg.312]    [Pg.66]    [Pg.287]    [Pg.401]    [Pg.165]    [Pg.83]    [Pg.41]    [Pg.40]    [Pg.104]    [Pg.114]    [Pg.461]    [Pg.463]    [Pg.211]    [Pg.24]    [Pg.2]    [Pg.202]   
See also in sourсe #XX -- [ Pg.2 ]




SEARCH



Commutability

Commutation

Commutativity

Commutator

Commute

© 2024 chempedia.info