Columns Contactors Towers

When compared to conventional systems (such as strippers, scrubbers, distillation columns, packed towers, bubble columns, evaporators, etc.), membrane contactors present several advantages, as reported in Figure 20.3. However, some drawbacks have also to be taken into account, as shown in Figure 20.4. 

There are several other types of apparata used for reactive absorption, though these are less widespread. In mechanically agitated bubble columns it can be assumed that both phases are ideally mixed, whereas in the jet absorber, the gas stream breaks on a liquid surface and is dispersed in the liquid. In spray towers and venturi scrubbers, liquid is sprayed as fine droplets. Thin-jilm contactors, in which liquid film is scrapped from the walls by impellers, are applied for reactive absorption in viscous liquids. Some units, such as wetted-wall columns, contactor, laminar jet absorber and disc (sphere) column are used mainly in laboratory. 

The second type of mass-exchange units is the differential (or continuous) contactor. In this category, the two phases flow through the exchanger in continuous contact throughout without intermediate phase separation and recontacting. Examples of differential contactors include packed columns (Fig. 2.6), spray towers (Fig. 2.7), and mechanically agitated units (Fig. 2.8). 

In the extraction process, the LPG from the prewash tower enters the bottom of an extractor column. The extractor is a liquid/liquid contactor in which the LPG is counter-currently contacted by a caustic solution. Another option is the use of a fiber film contacting device. The mercaptans dissolve in the caustic (Equation 1-14). The treated LPG leaves the top of the extractor and goes on to a settler, where entrained caustic is separated. 

Continuous changes in compositions of phases flowing in contact with each other are characteristic of packed towers, spray or wetted wall columns, and some novel equipment such as the FHGEE contactor (Fig. 13.14). The theory of mass transfer between phases and separation of mixtures under such conditions is based on a two-film theory. The concept is illustrated in Figure 13.15(a). 

For gas absorption, the equipment possibilities are generally packed columns plate distillation towers, possibly with mechanical agitation on every plate deep-bed contactors (bubble columns or sparged lagoons) and mechanically agitated vessels or lagoons. Packed towers and plate distillation columns are discussed elsewhere. Generally these... 

Contactors have a number of advantages compared to simple liquid/gas absorb-er/strippers or liquid/liquid extractors. Perhaps the most important advantage is high surface area per volume. The contact area of membrane contactors compared to traditional contactor columns is shown in Table 13.2. Membrane contactors provide 10-fold higher contactor areas than equivalent-sized towers. This makes membrane... 

Many modifications of the three types of contactors just discussed have been developed in an effort to reduce costs, reduce pressure drop, equalize vapor flow through each contactor, increase plate efficiencies, or, in general, improve the operating performance of the tower. An example of this for modification of bubble-cap towers is the old Uniflux tray originally developed by Socony-Vacuum, which consisted of a series of interlocking S-shaped sections which were assembled in the form of tunnel caps with slot outlets on one side only. Segmental downcomers, similar to the downcomers in conventional bubble-cap columns, were provided. The vapors issued from the Uniflux caps in... 

Distillation towers feed-tray location for, 10 optimum reflux ratio for, 371-376 specifications for, 16 (See also Bubble-cap contactors, Packed towers. Sieve trays, and Valve trays) Distribution costs, 194, 196, 207, 211 Distribution in statistical analyses, 745-746 Dividends, tax exemptions for, 259 Documentation, 137-149,452-476 Double-entry bookkeeping, 143-144 Downcomers in tray columns, 684-686 Drives, cost of 532-533 Dryers, cost of 713-716... 

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