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Coherence absence

A microwave pulse from a tunable oscillator is injected into the cavity by an anteima, and creates a coherent superposition of rotational states. In the absence of collisions, this superposition emits a free-mduction decay signal, which is detected with an anteima-coupled microwave mixer similar to those used in molecular astrophysics. The data are collected in the time domain and Fourier transfomied to yield the spectrum whose bandwidth is detemimed by the quality factor of the cavity. Hence, such instruments are called Fourier transfomi microwave (FTMW) spectrometers (or Flygare-Balle spectrometers, after the inventors). FTMW instruments are extraordinarily sensitive, and can be used to examine a wide range of stable molecules as well as highly transient or reactive species such as hydrogen-bonded or refractory clusters [29, 30]. [Pg.1244]

Related results of promotion (catalysis) and inliibition of stereonuitation by vibrational excitation have also been obtained for the much larger molecule, aniline-NHD (CgH NHD), which shows short-time chirality and stereonuitation [104. 105]. This kind of study opens the way to a new look at kinetics, which shows coherent and mode-selective dynamics, even in the absence of coherent external fields. The possibility of enforcing coherent dynamics by fields ( coherent control ) is discussed in chapter A3.13. [Pg.2144]

The only difficulty in this method (in addition to the calculations, which are easily carried out using computers) is the fact that it is impossible to analyse tables with values that are missing, so there is a need to choose substances for which there are a whole range of LC and LD values. Since this is impossible, three tables were used, which all have in common the L050 variables for rat and mouse, orally and by intraperitoneal means of penetration, so that the coherence of the three tables and a strong enough relationship between them could be ablished. The purpose was to determine, if, in the absence of one of the classification criteria set by regulation, it was possible to choose another available criterion to determine the risk level of toxicity. [Pg.136]

Elsewhere in this book, experiments are described which compare organically grown products with conventionally grown products. The next steps will be to interpret these differences in terms of their effects on human health and finding ways of improving crop quality in the production phase. This will require a coherent concept of food quality, a concept in which food quality is more than the sum of exterior characteristics some specific health components and the absence of harmful contaminants. Moreover, we need a concept that connects the different phases of plant growth to properties of the harvested product and to human or animal health. The IQC can meet these requirements. [Pg.70]

The banded coherency spectrum has an analogous definition (Yeung and Pope 1993) where the energy spectra are replaced with the spectra integrated over a finite wavenumber band. From the spectral time-evolution equations, it is easily shown that, in the absence of mean scalar gradients, the time evolution of the coherency spectrum is governed by 1 dPap Tap 1 Taa 1 Tpp ... [Pg.384]

Thus, as noted by Yeung andPope (1993), since the molecular diffusivities do not appear on the right-hand side, molecular differential diffusion affects the coherency only indirectly, i.e., through inter-scale transfer processes which propagate incoherency from small scales to large scales. The choice of the model for the scalar transfer spectra thus completely determines the long-time behavior of pap in the absence of mean scalar gradients. [Pg.384]

Let us examine the instability oi strained thin films. In Fig. 3, thin films of30 ML are coherently bonded to the hard substrates. The film phase has a misfit strain, e = 0.01, relative to the substrate phase, and the periodic length is equal to 200 a. The three interface energies are identical to each other = yiv = y = Y Both phases are elastically isotropic, but the shear modulus of the substrate is twice that of the film (p = 2p). On the left-hand side, an infinite-torque condition is imposed to the substrate-vapor and film-substrate interfaces, whereas torque terms are equal to zero on the right. In the absence of the coherency strain, these films are stable as their thickness is well over 16 ML. With a coherency strain, surface undulations induced by thermal fluctuations become growing waves. By the time of 2M, six waves are definitely seen to have established, and these numbers are in agreement with the continuum linear elasticity prediction [16]. [Pg.127]


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See also in sourсe #XX -- [ Pg.59 ]




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