Circular dicroism

In this context, one should bear in mind that the crystal structure may not exactly reflect the situation in solution however, it represents one possible low-energy conformation of the SO-SA complex. Other spectroscopic methods like NMR and FT-IR spectroscopy have been shown to be very helpful to study SO-SA complexation in solution and to verify the binding mechanisms found in the solid state. In this context circular dicroism spectroscopy should also be of high value. 

Chiroptical properties of isothiazole derivatives have been studied using circular dicroism (CD). Optically active sulfinamide R- +)-49a. (R=l-Ad) shows a positive first Cotton effect at 284nm while A (- -)-49b (R = 2,4,6-Me3C6H2) has a negative one at 277 nm <2005JOC868>. 

J. Christensen and J. W. Jaroszewski, Natural glycosides containing allopyranose from the passion fruit plant and circular dicroism of benzaldehyde cyanohydrin glycosides, Org. Lett., 3 (2001) 2193-2195. 

F gt3 SLt Continuous Variation Plots of the Molar Circular Dicroism at kl3 and U85 nm of c<, -Cyclodextrin epichlorohydrin Polymer Products and Methyl Oran — The fraction in which the molecular weight is less than 2000,... 

In this Section, we will analyze and compare the results obtained for plastocyanin and nitrosocyanin, in terms of chromophore structure, UV/VIS and circular dicroism spectrum and ESR parameter. 

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