1 -Chloro-2,2,2-trifluoropropane

Carbon tetrachloride, 0322 Carbon tetrafluoride, 0349 Carbon tetraiodide, 0525 f 1-Chlorobutane, 1637 f 2-Chlorobutane, 1638 f Chlorocyclopentane, 1923 f l-Chloro-l,l-dilluoroethane, 0731 Chlorodilluoromethane, 0369 f Chloroethane, 0848 Chloroform, 0372 f Chloromethane, 0432 f l-Chloro-3-methylbutane, 1986 f 2-Chloro-2-methylbutane, 1987 f Chloromethyl ethyl ether, 1246 f Chloromethyl methyl ether, 0850 f l-Chloro-2-methylpropane, 1639 f 2-Chloro-2-methylpropane, 1640 f 1-Chloropentane, 1988 f 1-Chloropropane, 1243 f 2-Chloropropane, 1244 f l-Chloro-3,3,3-trifluoropropane, 1127 1,2-Dibromoethane, 0785 Dibromomethane, 0395... 

Trichloro-3,3,3-trifluoropropane (26) with potassium hydroxide gives 1-chloro-3,3,3-tri-fluoroprop-l-yne (27).60... 

With bromine trifluonde and 1% tin tetrachlonde as a catalyst, 1,3-dichloro 2-fluoropropane gives 1,2,3 trifluoropropane Without the catalyst, l-chloro-2,3 difluoropropane provides a four-component product mixture 1,2,3-tnfluoro-propane, 3-chloro-l,l,2-tnfluoropropane, l-chloro-2,2,3-trifluoropropane, and 1,1,2,3-tetrafluoropropane [9] (equations 7 and 8)... 

Hexachlor6-3-fluoropropane (CHCI2CCI2CCI2F).30 In a 1-1. flask, a mixture of 1160 g. of 1,1,2,2,3,3,3-heptachloropropane and 740 g. of antimony trifluorodichloride is vigorously stirred so that the temperar ture does not exceed 50°. After the mixture has cooled to 30°, it is slowly heated to 130-140° and maintained at this temperature for five hours. It is then cooled, poured into water, washed with hydrochloric acid—to remove antimony salts—then with water, anchdried. The yield is 907 g. of reaction product containing approximately 60 g. of 1,1,2,2-tetrachloro-3,3,3-trifluoropropane (b.p. 130°), 315 g. of 1,1,2,2,3-penta-chloro-3,3-difluoropropane (b.p. 168°), and 435 g. of 1,1,2,2,3,3-hexa-chloro-3-fluoropropane (b.p. 210°). 

How does benzene react with 2-chloro-1,1,1-trifluoropropane in the Friedel-Crafts reaction, and what is the product E ... 

Together with 3-chloro-l. 1,2,2-tetrafluoropropane (12 %). f Together with 1,3-dichloro-t, 2,2-trifluoropropane (35 %). 

Chloro-4-(trifluoromethyl)benzene 3-Chloro-1,1,1-trifluoropropane 2-Chloro-2,4,4-trimethylpentane Chlorotrimethylstannane 2-Chloro-1,3,5-trinitrobenzene Chlorotrinitromethane Chlorotriphenylmethane... 

C3H4CIF3 3 -Chloro-1,1,1 -trifluoropropane 295.2 7.32 0.22361E+02 -0.68840E-01 0.60594E-04 275-313... 

Now let s make all this theory a little more real, and look at some molecules. Imagine a process (Figure 4.31,X = Cl) in which the (S) enantiomer of2-chlorohutane (rcc-butyl chloride) reacts with the two enantiomers of 2-chloro-l,l,l-trifluoropropane (Fig. 4.33). 

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