1 3-Chloro-6-methylbenzenesulfonamide

Dipping solution Dissolve 10 g trichloroacetic acid and 0.4 g chloramine T (N-chloro-4-methylbenzenesulfonamide sodium salt) in a mixture of 80 ml chloroform, 18 ml methanol and 2 ml water [11]. 

Ditosyl derivative of 1,4,7-oxadiazonane was synthesized from /V,/V -ditosyl diaminoethane and diethylene glycol ditosylate (see Scheme 42, Section 14.10.7.5) <2004T5799> or with l-chloro-2-(2-chloroethoxy)ethane <1998JRM1448>. Similarly, Richman-Atkins cyclization of ditosyl-substituted ethylenediamine with ditosylate of iV,iV-bis(2-hydroxyethyl)-4-methylbenzenesulfonamide gave the functionalized triazonanes <2003OBC2357>. 

Alkyl phenyl telluriums react with AT-chloro-A-sodio-4-methylbenzenesulfonamide in refluxing THF to yield terminal olefins from prim, alkyl groups and a mixture of 1 -alkenes and 2-alkenes from sec. alkyl groups. Diorgano tellurium imides were postulated as intermediates. Considering the synthesis of the alkyl phenyl tellurium from an alkyl halide and benzenetellurolate, the overall reaction is the conversion of an alkyl halide to an olefin. Starting with lithiomethyl phenyl tellurium and an alkyl halide, the resulting olefin will have one carbon atom more than the alkyl halide. ... 

N-Chloro-4-methylbenzenesulfonamide sodium salt. See Chloramine-T Chloromethyl bromide. See Bromochloromethane... 

Synonyms N-sodium-N-chloro-p-toluene sulfonamide sodium p-toluenesulfonchloramide trihydrate Chloramine T sodium salt p-toluenesulfonchloramide sodium salt sodium p-toluenesulfonchloramine N-chloro-4-methylbenzenesulfonamide sodium salt (N-chloro-p-toluenesulfonamideo)sodium Aktiven Chloraseptine Chlorazene Chlorazone Clorina Euclorina Gansil Gyneclorina Halamid Mianine Tochlorine Tolamine N-chloro-p-toluene sulfonamide sodium salt N-chloro-p-toluenesulfonamide sodium salt trihydrate chloro-4-methylbenzenesulfonamide, sodium salt sodium N-chloro-p-toluenesulfonchloramide tosylchloramide sodium sodium N-chloro-p-toluenesulfonamidate... 

Preparative Methods. Several methods have been published for the synthesis of W-(diphenylmethylene)-4-methylbenzenesul-fonamide (2), but only two have been applied to the preparation of 7V-(diphenylmethylene)benzenesulfonamide (1). Thus, condensation of dichlorodiphenylmethane (3) with benzenesulfonamide (4, R = H) or 4-methylbenzenesulfonamide (4, R = CH3) in the presence of AICI3 at room temperature and 1,2-dichloroethane as solvent leads to the corresponding products in high yields (eq 1). Lower yields of products 1 and 2 are obtained when either diphenyldiazomethane (5) or benzophenone hydrazone (6) condenses with W-chloro-W-sodiumbenzenesulfonamide (Chlor-amine-B) (7, R = H) or with its 4-methylphenyl derivative... 

Amide, H-chloro [127-65-1]. Chloramine T. -Chloro-4-methylbenzenesulfonamide, 9CI. N-C/i/oro-p-toluene sulfonamide... 

SH-form, 5-Me, in N-00096 6-(5-Chloro-2-hydroxy-4-sulfophenylazo)-5-hydroxy-1 -naphthalenesulfonic acid Di-Na salt, in C-00161 A -(2-Aminophenyl)-4-methylbenzenesulfonamide, A-00326... 

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