1- Chloro-2-methyl propane

By contrast, hydrolysis of the tertiary halide 2-chloro-2-methyl-propane (3,t-butyl chloride) in base is found kinetically to follow equation [2], i.e. as the rate is independent of [eOH], this can play no part in the rate-limiting step. This has been interpreted as indicating that the halide undergoes slow ionisation (in fact, completion of the R->-Cl polarisation that has already been shown to be present in such a molecule) as the rate-limiting step to yield the ion pair R Cle (4) followed by rapid, non rate-limiting attack by eOH or, if that is suitable, by solvent, the latter often predominating because of its very high concentration ... 

Bassam Z. Shakhashiri, "Hydrolysis of 2-chloro-2-methylpropane," Chemical Demonstrations, A Handbook for Teachers of Chemistry, Vol. 4 (The University of Wisconsin Press, Madison, 1992), pp. 56-64. The time required for the color change in this reaction is shown to increase with increasing sodium hydroxide concentration, decrease with increasing 2-chloro-2-methylpropane concentration, and increase as the ratio of water/acetone increases. These observations are related to the mechanism of 2-chloro-2-methyl-propane hydrolysis. 

MWP. However, the quantity of chlorinated hydrocarbons during MWP degradation was higher than 3P/PVC/PET and 3P/PVC degradation liquid products. Gas chromatography equipped with an atomic emission detector (GC-AED), was used for selective detection of Cl in the liquid products. As can be seen from Figure 18.19, the presence of PET produced the additional chlorinated hydrocarbons than 3P/PVC. The liquid products were analyzed by GC-MS to identify the compounds. The presence of chlorinated compounds with model and MWP were observed as 2-chloro-2-phenyl propane, 2-chloro-2-methyl propane, 2-chloro-2-methyl pentane, and a-chloro ethyl benzene. 

Just as the L2 reaction is analogous to the Sfs 2 reaction, the Sjsjl reactiem has a close analog called the El reaction (for elimination, unimolcailar). The U1 reaction can be formulated as shown in Figure 11.21 for the elimination of HCl from 2-chloro-2-methyl propane. 

Figure 16. Current decay curves the natural logarithm of the steady-state oxidation plateau current of radical anions (mediators) plotted against time (s) for the following four combinations of mediator/substrate benzophenone/l-bromo-2,2-dimethylpropane (-(-) perylene/l-bromo-2,2-dimethylpropane (x) perylene/l-bromoadamantane ( ) and quinoxaline/2-chloro-2-methyl-propane (O). All measurements were obtained with a 10-pm platinum disk electrode in DMF/0.1 M BU4NBF4 at 22°C. From S. U. Pedersen and K. Daasbjerg, Acta Chem. Scand, 43 30 (1989) [36],...

Dr. Don T. Doit wanted to synthesize the anesthetic 2-ethoxy-2-methylpropane. He used ethoxide ion and 2-chloro-2-methyl-propane for his synthesis and ended up with very little ether. What was the predominant product of his synthesis What reagents should he have used ... 

The thiazoline derivative 109 was obtained as a single isomer by condensation of the corresponding 1,6-D-galactodialdehyde diacetal with 2-chloro-2-methyl-propanal, ammonia and sodium sulfide/ The multi-step synthesis of 3-trialkyl-silypyrazole derivatives such as 110 from 5,6-dihydroxy-sugar derivatives has been described/ ... 

CHs-C-CHj tert-butyl chloride 2-chloro-2-methyl propane... 

Figure 3.1 Change in the concentration of HCl with time in the solvolysis of 2-chloro-2-methyl-propane in the presence of 40% ethanol-water solution at 20 °C.

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