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Chiral sulfinamides, application

NMR spectral differentiation of enantiomers as solutes in chiral solvents has been achieved with sulfoxides, sulfinates, thiosulfinates, sulfinamides, and sulfites (86,108,242). The usefulness and high sensitivity of this method is confirmed by its successful application... [Pg.404]

As discussed above the kinetic stability of allylic sulfoximines prevents them from going downhill to the thermodynamically favored sulfinamides, which in turn is a precondition for their successful application as solutions for asymmetric d -synthons [ 13-15,20-32]. On the other hand, if it would be possible to make them rearrange to allylic amines with 1,3-chirality transfer, this would be an interesting entry to this class of compounds (Scheme 6). ... [Pg.7]

Han Z, Krischnamurthy D, Pfium D, Grover P, Wald SA, Senanayake CH. First application of tunable alkyl or aryl sulfinamides to the stereoselective synthesis of a chiral... [Pg.67]

See other pages where Chiral sulfinamides, application is mentioned: [Pg.41]    [Pg.48]    [Pg.51]    [Pg.198]    [Pg.252]    [Pg.250]    [Pg.278]    [Pg.41]    [Pg.52]   
See also in sourсe #XX -- [ Pg.48 , Pg.49 , Pg.50 , Pg.51 ]



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