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Chiral ligands sulfur-palladium complexes

In 2004, Molander et al. developed another type of chiral sulfur-containing ligands for the intermolecular Heck reaction. Thus, their corresponding novel cyclopropane-based phosphorus/sulfur palladium complexes proved to be active as catalysts for the reaction between phenyltriflate and dihydrofuran, providing at high temperature a mixture of the expected product and its iso-merised analogue (Scheme 7.7). The major isomer C was obtained with a maximum enantioseleetivity of 63% ee. [Pg.239]

D.ii. Palladium(II) Complexes with Chiral Phosphorus, Nitrogen, or Sulfur Ligands... [Pg.109]


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Chiral complexes

Chiral ligands

Chirality complexes

Chirality/Chiral complexes

Ligands chirality

Palladium complexes chiral

Palladium complexes ligands

Palladium ligands

Palladium sulfuration

Sulfur complexes

Sulfur ligands palladium complexes

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