Chemically induced dynamic nuclear electron transfer

Chain processes, free radical, in aliphatic systems involving an electron transfer reaction, 23,271 Charge density-NMR chemical shift correlation in organic ions, 11,125 Chemically induced dynamic nuclear spin polarization and its applications, 10, 53 Chemiluminescence of organic compounds, 18,187... 

Further evidence for the formation of alkene radical cations derives from the work of Giese, Rist, and coworkers who observed a chemically induced dynamic nuclear polarization (CIDNP) effect on the dihydrofuran 6 arising from fragmentation of radical 5 and electron transfer from the benzoyl radical within the solvent cage (Scheme 6) [67]. 

Several lines of evidence indicate that the oxidative addition of RX to the electron-rich early-metal complex Cp2Zr(II)L2also occurs by a radical pathway initiated by electron transfer (Equation 7.8). - Zr(III) intermediates were observed by EPR, and evidence for effects of CIDNP (Chemically Induced Dynamic Nuclear Polarization) were observed in... 

Goez, M., Rozwadowski, J., and Marciniak, B., Photoinduced electron transfer, decarboxylation and radical fragmentation of cysteine derivatives a chemically induced dynamic nuclear polarization study, /. Am. Chem. Soc., 118, 2882, 1996. 

A triplex electron-transfer mechanism involving interaction of dibenzoylmethanatoboron difluoride (DMB) and an aromatic co-sensitizer (A — toluene, ethylbenzene, biphenyl, and durene) with N was suggested based on the results from a chemically induced dynamic nuclear polarization study of the reaction ... 

Becker, H. G. O., Pfeifer, D., and Urban, K., Evidence for the Marcus inverted region of back-electron transfer in solution by means of chemically induced dynamic nuclear polarization, /. Chem. Soc., Faraday Trans. 2, 85,1765, 1989. 

The seminal work of Marcus and Hush has had a significant impact on the development of PET. Pioneering efforts by Sutin, Hopfield, Jortner, and others established the connection between thermal electron transfer and photoelectron transfer [6]. This work set the stage for a notable series of experiments where laser flash spectroscopy [7], chemically induced nuclear polarization [8], resonance Raman spectroscopy [9], time-resolved microwave conductivity [10], and time-resolved photoacoustic calorimetry [11], to site only a few examples, have been successfully employed to chart the dynamics of PET in homogeneous solution, the solid-state, and organized assemblies. 

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