Marcus inverted region

Guldi D M and Asmus K-D 1997 Electron transfer from Cjg D2) and Cjg C2 ) to radical cations of various arenes evidence for the Marcus inverted region J. Am. Chem. See. 119 5744-5... 

Gould I R, Ege D, Mattes S L and Farid S 1987 Return electron transfer with geminate radical ion pairs - observation of the Marcus inverted region J. Am. Chem. Soc. 109 3794-6... 

The PET process in the dyad is located in the normal region of the Marcus curve, while the back-electron transfer from Q0 to ZnPor+ is in the Marcus inverted region (Figure 6.27). 

The further improvement of the product yield (100%) was achieved by employing AcrPh + instead of AcrH + and this can also be ascribed to the slower back-electron transfer rate for the former than the latter [109]. In the Marcus-inverted region, the back-electron transfer becomes slower with increasing the driving force. Because the EZx value of AcrPh" (E°x versus SCE = - 0.55 V)... 

Fig. 18 Free energy surfaces illustrating the activation energy AG for charge recombination in the Marcus inverted region and the coupling term //,y between the initial state, i, and the final state, y...

Stick RV (1997) The Synthesis of Novel Enzyme Inhibitors and Their Use in Defining the Active Sites of Glycan Hydrolases. 187 187-213 Stutz AE, see de Raadt A (1997) 187 157-186 Stumpe R, see Kim JI (1990) 157 129-180 Suami T (1990) Chemistry of Pseudo-sugars. 154 257-283 Suppan P (1992) The Marcus Inverted Region. 153 95-130 Suzuki N (1990) Radiometric Determination of Trace Elements. 157 35-56 Tabakovic I (1997) Anodic Synthesis of Heterocyclic Compounds. 185 87-140 Takahashi Y (1995) Identification of Structural Similarity of Organic Molecules. 174 105-134 Tasi G, Palinkd I (1995) Using Molecular Electrostatic Potentid Maps for Similarity Studies. 174 45-72... 

The free energy for ground-state product formation is correspondingly so negative that this pathway lies in the Marcus inverted region. Consequently both, energetically... 

Figure 9 Activated versus tunneling behavior in the Marcus inverted region.

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